Functionalized 1′-substituted iodoferrocenes and their Pd-catalyzed Heck cross-coupling reactions

Max Roemer; Bruno Donnadieu; Christian A. Nijhuis

doi:10.1002/ejic.201501451

Functionalized 1′-substituted iodoferrocenes and their Pd-catalyzed Heck cross-coupling reactions

Max Roemer, Bruno Donnadieu, Christian A. Nijhuis^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

This paper describes the preparation of a variety of 1′-substituted iodoferrocenes from 1-iodo-1′-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

Original language	English
Pages (from-to)	1314-1318
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	9
DOIs	https://doi.org/10.1002/ejic.201501451
Publication status	Published - Mar 2016
Externally published	Yes

Keywords

Iodoferrocenes
Bridged ferrocenes
Cross-coupling
Homogeneous catalysis
Acylation

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10.1002/ejic.201501451

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abstract = "This paper describes the preparation of a variety of 1′-substituted iodoferrocenes from 1-iodo-1′-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.",

keywords = "Iodoferrocenes, Bridged ferrocenes, Cross-coupling, Homogeneous catalysis, Acylation",

author = "Max Roemer and Bruno Donnadieu and Nijhuis, {Christian A.}",

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AU - Donnadieu, Bruno

AU - Nijhuis, Christian A.

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N2 - This paper describes the preparation of a variety of 1′-substituted iodoferrocenes from 1-iodo-1′-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

AB - This paper describes the preparation of a variety of 1′-substituted iodoferrocenes from 1-iodo-1′-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

KW - Iodoferrocenes

KW - Bridged ferrocenes

KW - Cross-coupling

KW - Homogeneous catalysis

KW - Acylation

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DO - 10.1002/ejic.201501451

M3 - Article

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SP - 1314

EP - 1318

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 9

ER -

Functionalized 1′-substituted iodoferrocenes and their Pd-catalyzed Heck cross-coupling reactions

Abstract

Keywords

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