Functionalized 1′-substituted iodoferrocenes and their Pd-catalyzed Heck cross-coupling reactions

Max Roemer, Bruno Donnadieu, Christian A. Nijhuis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

This paper describes the preparation of a variety of 1′-substituted iodoferrocenes from 1-iodo-1′-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

Original languageEnglish
Pages (from-to)1314-1318
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number9
DOIs
Publication statusPublished - Mar 2016
Externally publishedYes

Keywords

  • Iodoferrocenes
  • Bridged ferrocenes
  • Cross-coupling
  • Homogeneous catalysis
  • Acylation

Fingerprint

Dive into the research topics of 'Functionalized 1′-substituted iodoferrocenes and their Pd-catalyzed Heck cross-coupling reactions'. Together they form a unique fingerprint.

Cite this