Furan-containing gem-bromonitroethenes

synthesis and reaction with morpholine

S. S. Eliseenko*, S. V. Makarenko, V. M. Berestovitskaya

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The first time the representative of furan-containing gem-bromonitroethenes 5-nitro-2-(2-bromo-2-nitro-ethenyl)furan was synthesized by bromination of 5-nitro-2-(2-nitroethenyl)furan followed by dehydrohalogenation of the dibromide. Morpholine adducts of the synthesized β-substituted gem-bromonitroethene and its analog with a 5-bromo-2-furyl substituent were obtained. The structures of the gem-bromonitroethenes and aza adducts were characterized by spectral methods (IR, UV, 1H, and 13C-{1H} NMR, including 1H-13C HMQC and HMBC).

Original languageEnglish
Pages (from-to)1424-1430
Number of pages7
JournalRussian Journal of General Chemistry
Volume85
Issue number6
DOIs
Publication statusPublished - 24 Jun 2015
Externally publishedYes

Keywords

  • furan
  • gem-bromonitroethene
  • morpholine
  • nucleophilic addition

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