Halogen bonding influences perylene-core twists in non-core substituted perylene tetraesters

Jonathan P. Wojciechowski; Adam D. Martin; Mohan Bhadbhade; James E. A. Webb; Pall Thordarson

doi:10.1039/c6ce00929h

Halogen bonding influences perylene-core twists in non-core substituted perylene tetraesters

Jonathan P. Wojciechowski, Adam D. Martin, Mohan Bhadbhade, James E. A. Webb, Pall Thordarson

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X⋯O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects its spectral properties. We show this interaction exists in both the solution and solid state through spectroscopy studies and single crystal analysis.

Original language	English
Pages (from-to)	4513-4517
Number of pages	5
Journal	CrystEngComm
Volume	18
Issue number	24
DOIs	https://doi.org/10.1039/c6ce00929h
Publication status	Published - 2016
Externally published	Yes

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84975513730&doi=10.1039%2fc6ce00929h&partnerID=40&md5=b5997af2d0bb4f8e5b51a7320b761f83

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abstract = "Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X⋯O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects its spectral properties. We show this interaction exists in both the solution and solid state through spectroscopy studies and single crystal analysis.",

author = "Wojciechowski, {Jonathan P.} and Martin, {Adam D.} and Mohan Bhadbhade and Webb, {James E. A.} and Pall Thordarson",

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AU - Martin, Adam D.

AU - Bhadbhade, Mohan

AU - Webb, James E. A.

AU - Thordarson, Pall

PY - 2016

Y1 - 2016

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AB - Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X⋯O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects its spectral properties. We show this interaction exists in both the solution and solid state through spectroscopy studies and single crystal analysis.

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DO - 10.1039/c6ce00929h

M3 - Article

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JO - CrystEngComm

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IS - 24

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Halogen bonding influences perylene-core twists in non-core substituted perylene tetraesters

Abstract

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