Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones

James A. Moore*, Ben Staskun, John F. Blount

*Corresponding author for this work

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

1-Acyl-2-(alkoxymethyl)tetrahydropyridazinones 8 are obtained from the bicyclic ketones 1 on heating in alcohol or alcohol-benzene mixtures and are suggested to arise by trapping of the intermediate 10. A pathway from 10 to the bicyclic pyrrolinones 2 is suggested (Scheme II).

Original languageEnglish
Pages (from-to)3156-3159
Number of pages4
JournalJournal of Organic Chemistry
Volume41
Issue number19
Publication statusPublished - 1976

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