Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones

James A. Moore; Ben Staskun; John F. Blount

Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones

James A. Moore^*, Ben Staskun, John F. Blount

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

1-Acyl-2-(alkoxymethyl)tetrahydropyridazinones 8 are obtained from the bicyclic ketones 1 on heating in alcohol or alcohol-benzene mixtures and are suggested to arise by trapping of the intermediate 10. A pathway from 10 to the bicyclic pyrrolinones 2 is suggested (Scheme II).

Original language	English
Pages (from-to)	3156-3159
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	41
Issue number	19
Publication status	Published - 1976

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title = "Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones",

abstract = "1-Acyl-2-(alkoxymethyl)tetrahydropyridazinones 8 are obtained from the bicyclic ketones 1 on heating in alcohol or alcohol-benzene mixtures and are suggested to arise by trapping of the intermediate 10. A pathway from 10 to the bicyclic pyrrolinones 2 is suggested (Scheme II).",

author = "Moore, {James A.} and Ben Staskun and Blount, {John F.}",

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T1 - Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones

AU - Moore, James A.

AU - Staskun, Ben

AU - Blount, John F.

PY - 1976

Y1 - 1976

N2 - 1-Acyl-2-(alkoxymethyl)tetrahydropyridazinones 8 are obtained from the bicyclic ketones 1 on heating in alcohol or alcohol-benzene mixtures and are suggested to arise by trapping of the intermediate 10. A pathway from 10 to the bicyclic pyrrolinones 2 is suggested (Scheme II).

AB - 1-Acyl-2-(alkoxymethyl)tetrahydropyridazinones 8 are obtained from the bicyclic ketones 1 on heating in alcohol or alcohol-benzene mixtures and are suggested to arise by trapping of the intermediate 10. A pathway from 10 to the bicyclic pyrrolinones 2 is suggested (Scheme II).

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M3 - Article

AN - SCOPUS:33847799372

SN - 0022-3263

VL - 41

SP - 3156

EP - 3159

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 19

ER -

Heterocyclic studies. 44. Thermal rearrangement of 2-acyl-1,2-diazabicycloheptenones

Abstract

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