Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system

James A. Moore; Ben Staskun

Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system

James A. Moore^*, Ben Staskun

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The 2,6-diazabicyclic carbinolamine 17 has been isolated from the reaction of the 1,2-diazabicyclic ketone 1 in methanol plus Et ₃N; 17 gives the same products (13 and 14) on further reaction in methanol as does 1. The reaction of ketone 1b with base gives the enamino ketone 30 plus glycine, indicating attack at the carbonyl group. Four reaction pathways of 1 are summarized.

Original language	English
Pages (from-to)	4021-4025
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	43
Issue number	21
Publication status	Published - 1978

Cite this

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title = "Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system",

abstract = "The 2,6-diazabicyclic carbinolamine 17 has been isolated from the reaction of the 1,2-diazabicyclic ketone 1 in methanol plus Et 3N; 17 gives the same products (13 and 14) on further reaction in methanol as does 1. The reaction of ketone 1b with base gives the enamino ketone 30 plus glycine, indicating attack at the carbonyl group. Four reaction pathways of 1 are summarized.",

author = "Moore, {James A.} and Ben Staskun",

year = "1978",

language = "English",

volume = "43",

pages = "4021--4025",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

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T1 - Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system

AU - Moore, James A.

AU - Staskun, Ben

PY - 1978

Y1 - 1978

N2 - The 2,6-diazabicyclic carbinolamine 17 has been isolated from the reaction of the 1,2-diazabicyclic ketone 1 in methanol plus Et 3N; 17 gives the same products (13 and 14) on further reaction in methanol as does 1. The reaction of ketone 1b with base gives the enamino ketone 30 plus glycine, indicating attack at the carbonyl group. Four reaction pathways of 1 are summarized.

AB - The 2,6-diazabicyclic carbinolamine 17 has been isolated from the reaction of the 1,2-diazabicyclic ketone 1 in methanol plus Et 3N; 17 gives the same products (13 and 14) on further reaction in methanol as does 1. The reaction of ketone 1b with base gives the enamino ketone 30 plus glycine, indicating attack at the carbonyl group. Four reaction pathways of 1 are summarized.

UR - http://www.scopus.com/inward/record.url?scp=33947093950&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33947093950

SN - 0022-3263

VL - 43

SP - 4021

EP - 4025

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system

Abstract

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