Heterocyclic studies. 46. Reaction pathways of the 2-acyl-1,2-diazabicyclo[3.2.0]-3-hepten-6-one system

James A. Moore*, Ben Staskun

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The 2,6-diazabicyclic carbinolamine 17 has been isolated from the reaction of the 1,2-diazabicyclic ketone 1 in methanol plus Et 3N; 17 gives the same products (13 and 14) on further reaction in methanol as does 1. The reaction of ketone 1b with base gives the enamino ketone 30 plus glycine, indicating attack at the carbonyl group. Four reaction pathways of 1 are summarized.

Original languageEnglish
Pages (from-to)4021-4025
Number of pages5
JournalJournal of Organic Chemistry
Volume43
Issue number21
Publication statusPublished - 1978

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