Heterogeneity in dye-TiO2 interactions dictate charge transfer efficiencies for diketopyrrolopyrrole-based polymer sensitized solar cells

Ajay Jha, Vineeth B. Yasarapudi, Hadiya Jasbeer, Catherine Kanimozhi, Satish Patil, Jyotishman Dasgupta*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)


Power conversion efficiency of a solar cell is a complex parameter which usually hides the molecular details of the charge generation process. For rationally tailoring the overall device efficiency of the dye-sensitized solar cell, detailed molecular understanding of photoinduced reactions at the dye-TiO2 interface has to be achieved. Recently, near-IR absorbing diketopyrrolopyrrolebased (DPP) low bandgap polymeric dyes with enhanced photostabilities have been used for TiO2 sensitization with moderate efficiencies. To improve the reported device performances, a critical analysis of the polymer-TiO2 interaction and electron transfer dynamics is imperative. Employing a combination of time-resolved optical measurements complemented by low temperature EPR and steady-state Raman spectroscopy on polymer-TiO2 conjugates, we provide direct evidence for photoinduced electron injection from the TDPP-BBT polymer singlet state into TiO2 through the C=O group of the DPP-core. A detailed excited state description of the electron transfer process in films reveals instrument response function (IRF) limited (<110 fs) charge injection from a minor polymer fraction followed by a picosecond recombination. The major fraction of photoexcited polymers, however, does not show injection indicating pronounced ground state heterogeneity induced due to nonspecific polymer-TiO2 interactions. Our work therefore underscores the importance of gathering molecular-level insight into the competitive pathways of ultrafast charge generation along with probing the chemical heterogeneity at the nanoscale within the polymer-TiO2 films for optimizing photovoltaic device efficiencies.

Original languageEnglish
Pages (from-to)29650-29662
Number of pages13
JournalJournal of Physical Chemistry C
Issue number51
Publication statusPublished - 26 Dec 2014
Externally publishedYes


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