High-conductive organometallic molecular wires with delocalized electron systems strongly coupled to metal electrodes

Florian Schwarz, Georg Kastlunger, Franziska Lissel, Heike Riel, Koushik Venkatesan*, Heinz Berke, Robert Stadler, Emanuel Lörtscher

*Corresponding author for this work

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Besides active, functional molecular building blocks such as diodes or switches, passive components, for example, molecular wires, are required to realize molecular-scale electronics. Incorporating metal centers in the molecular backbone enables the molecular energy levels to be tuned in respect to the Fermi energy of the electrodes. Furthermore, by using more than one metal center and sp-bridging ligands, a strongly delocalized electron system is formed between these metallic "dopants", facilitating transport along the molecular backbone. Here, we study the influence of molecule-metal coupling on charge transport of dinuclear X(PP)2FeC4Fe(PP)2X molecular wires (PP = Et2PCH2CH2PEt2); X = CN (1), NCS (2), NCSe (3), C4SnMe3 (4), and C2SnMe3 (5) under ultrahigh vacuum and variable temperature conditions. In contrast to 1, which showed unstable junctions at very low conductance (8.1 × 10-7 G0), 4 formed a Au-C4FeC4FeC4-Au junction 4′ after SnMe3 extrusion, which revealed a conductance of 8.9 × 10-3 G0, 3 orders of magnitude higher than for 2 (7.9 × 10-6 G0) and 2 orders of magnitude higher than for 3 (3.8 × 10-4 G0). Density functional theory (DFT) confirmed the experimental trend in the conductance for the various anchoring motifs. The strong hybridization of molecular and metal states found in the C-Au coupling case enables the delocalized electronic system of the organometallic Fe2 backbone to be extended over the molecule-metal interfaces to the metal electrodes to establish high-conductive molecular wires.

Original languageEnglish
Pages (from-to)5932-5940
Number of pages9
JournalNano Letters
Volume14
Issue number10
DOIs
Publication statusPublished - 8 Oct 2014
Externally publishedYes

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Keywords

  • Break-Junctions
  • Density Functional Theory
  • Electronic Transport
  • Molecular Wire
  • Organometallic Compounds
  • Single-Molecule Junctions

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