TY - JOUR
T1 - High-conductive organometallic molecular wires with delocalized electron systems strongly coupled to metal electrodes
AU - Schwarz, Florian
AU - Kastlunger, Georg
AU - Lissel, Franziska
AU - Riel, Heike
AU - Venkatesan, Koushik
AU - Berke, Heinz
AU - Stadler, Robert
AU - Lörtscher, Emanuel
PY - 2014/10/8
Y1 - 2014/10/8
N2 - Besides active, functional molecular building blocks such as diodes or switches, passive components, for example, molecular wires, are required to realize molecular-scale electronics. Incorporating metal centers in the molecular backbone enables the molecular energy levels to be tuned in respect to the Fermi energy of the electrodes. Furthermore, by using more than one metal center and sp-bridging ligands, a strongly delocalized electron system is formed between these metallic "dopants", facilitating transport along the molecular backbone. Here, we study the influence of molecule-metal coupling on charge transport of dinuclear X(PP)2FeC4Fe(PP)2X molecular wires (PP = Et2PCH2CH2PEt2); X = CN (1), NCS (2), NCSe (3), C4SnMe3 (4), and C2SnMe3 (5) under ultrahigh vacuum and variable temperature conditions. In contrast to 1, which showed unstable junctions at very low conductance (8.1 × 10-7 G0), 4 formed a Au-C4FeC4FeC4-Au junction 4′ after SnMe3 extrusion, which revealed a conductance of 8.9 × 10-3 G0, 3 orders of magnitude higher than for 2 (7.9 × 10-6 G0) and 2 orders of magnitude higher than for 3 (3.8 × 10-4 G0). Density functional theory (DFT) confirmed the experimental trend in the conductance for the various anchoring motifs. The strong hybridization of molecular and metal states found in the C-Au coupling case enables the delocalized electronic system of the organometallic Fe2 backbone to be extended over the molecule-metal interfaces to the metal electrodes to establish high-conductive molecular wires.
AB - Besides active, functional molecular building blocks such as diodes or switches, passive components, for example, molecular wires, are required to realize molecular-scale electronics. Incorporating metal centers in the molecular backbone enables the molecular energy levels to be tuned in respect to the Fermi energy of the electrodes. Furthermore, by using more than one metal center and sp-bridging ligands, a strongly delocalized electron system is formed between these metallic "dopants", facilitating transport along the molecular backbone. Here, we study the influence of molecule-metal coupling on charge transport of dinuclear X(PP)2FeC4Fe(PP)2X molecular wires (PP = Et2PCH2CH2PEt2); X = CN (1), NCS (2), NCSe (3), C4SnMe3 (4), and C2SnMe3 (5) under ultrahigh vacuum and variable temperature conditions. In contrast to 1, which showed unstable junctions at very low conductance (8.1 × 10-7 G0), 4 formed a Au-C4FeC4FeC4-Au junction 4′ after SnMe3 extrusion, which revealed a conductance of 8.9 × 10-3 G0, 3 orders of magnitude higher than for 2 (7.9 × 10-6 G0) and 2 orders of magnitude higher than for 3 (3.8 × 10-4 G0). Density functional theory (DFT) confirmed the experimental trend in the conductance for the various anchoring motifs. The strong hybridization of molecular and metal states found in the C-Au coupling case enables the delocalized electronic system of the organometallic Fe2 backbone to be extended over the molecule-metal interfaces to the metal electrodes to establish high-conductive molecular wires.
KW - Break-Junctions
KW - Density Functional Theory
KW - Electronic Transport
KW - Molecular Wire
KW - Organometallic Compounds
KW - Single-Molecule Junctions
UR - http://www.scopus.com/inward/record.url?scp=84907861806&partnerID=8YFLogxK
U2 - 10.1021/nl5029045
DO - 10.1021/nl5029045
M3 - Article
C2 - 25233125
AN - SCOPUS:84907861806
SN - 1530-6984
VL - 14
SP - 5932
EP - 5940
JO - Nano Letters
JF - Nano Letters
IS - 10
ER -