High-resolution spectroscopy of the v3 band of WF6 and ReF6 in a supersonic jet

V. Boudon; M. Rotger; Y. He; H. Hollenstein; M. Quack; U. Schmitt

doi:10.1063/1.1475754

High-resolution spectroscopy of the v₃ band of WF₆ and ReF₆ in a supersonic jet

V. Boudon, M. Rotger, Y. He, H. Hollenstein, M. Quack^*, U. Schmitt

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A systematic understanding of the v₃ fundamental rovibronic structure of transition metal hexafluorides in general and WF₆ and ReF₆ in particular is discussed. The high resolution Fourier-transform infrared (FTIR) and diode laser spectra obtained and analyzed confirm the theoretical expectation of completely different spectral structure of two prototypes for a closed shell hexafluoride molecule. The rovibrational spectra of the v₃ stretching fundamental of WF₆ show a simple structure under conditions of supersonic jet cooling, allowing for a straightforward analysis.

Original language	English
Pages (from-to)	3196-3207
Number of pages	12
Journal	Journal of Chemical Physics
Volume	117
Issue number	7
DOIs	https://doi.org/10.1063/1.1475754
Publication status	Published - 15 Aug 2002
Externally published	Yes

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abstract = "A systematic understanding of the v3 fundamental rovibronic structure of transition metal hexafluorides in general and WF6 and ReF6 in particular is discussed. The high resolution Fourier-transform infrared (FTIR) and diode laser spectra obtained and analyzed confirm the theoretical expectation of completely different spectral structure of two prototypes for a closed shell hexafluoride molecule. The rovibrational spectra of the v3 stretching fundamental of WF6 show a simple structure under conditions of supersonic jet cooling, allowing for a straightforward analysis.",

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AU - Boudon, V.

AU - Rotger, M.

AU - He, Y.

AU - Hollenstein, H.

AU - Quack, M.

AU - Schmitt, U.

PY - 2002/8/15

Y1 - 2002/8/15

N2 - A systematic understanding of the v3 fundamental rovibronic structure of transition metal hexafluorides in general and WF6 and ReF6 in particular is discussed. The high resolution Fourier-transform infrared (FTIR) and diode laser spectra obtained and analyzed confirm the theoretical expectation of completely different spectral structure of two prototypes for a closed shell hexafluoride molecule. The rovibrational spectra of the v3 stretching fundamental of WF6 show a simple structure under conditions of supersonic jet cooling, allowing for a straightforward analysis.

AB - A systematic understanding of the v3 fundamental rovibronic structure of transition metal hexafluorides in general and WF6 and ReF6 in particular is discussed. The high resolution Fourier-transform infrared (FTIR) and diode laser spectra obtained and analyzed confirm the theoretical expectation of completely different spectral structure of two prototypes for a closed shell hexafluoride molecule. The rovibrational spectra of the v3 stretching fundamental of WF6 show a simple structure under conditions of supersonic jet cooling, allowing for a straightforward analysis.

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High-resolution spectroscopy of the v₃ band of WF₆ and ReF₆ in a supersonic jet

Abstract

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