Higher order hyperfine terms in the spin Hamiltonian

R. M. Golding; L. C. Stubbs

doi:10.1098/rspa.1978.0148

Higher order hyperfine terms in the spin Hamiltonian

R. M. Golding, L. C. Stubbs

Research output: Contribution to journal › Article › peer-review

Abstract

The higher order hyperfine terms in the spin Hamiltonian are evaluated for the general case where the hyperfine interaction raises from the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum interactions of a d-electron associated dominantly with one nucleus coupling with another nucleus, where the electronic wavefunction is described by a Slater-type orbital. The method handles long range and short range coupling including the free atom case. The case for a one-electron transition metal ion in a crystal field environment of octahedral symmetry is examined.

Original language	English
Pages (from-to)	525-536
Number of pages	12
Journal	Proceedings of The Royal Society of London, Series A: Mathematical and Physical Sciences
Volume	362
DOIs	https://doi.org/10.1098/rspa.1978.0148
Publication status	Published - 1978
Externally published	Yes

Access to Document

10.1098/rspa.1978.0148

Cite this

@article{f203d54ef24548b688ffa1b7d022b718,

title = "Higher order hyperfine terms in the spin Hamiltonian",

abstract = "The higher order hyperfine terms in the spin Hamiltonian are evaluated for the general case where the hyperfine interaction raises from the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum interactions of a d-electron associated dominantly with one nucleus coupling with another nucleus, where the electronic wavefunction is described by a Slater-type orbital. The method handles long range and short range coupling including the free atom case. The case for a one-electron transition metal ion in a crystal field environment of octahedral symmetry is examined.",

author = "Golding, {R. M.} and Stubbs, {L. C.}",

year = "1978",

doi = "10.1098/rspa.1978.0148",

language = "English",

volume = "362",

pages = "525--536",

journal = "Proceedings of The Royal Society of London, Series A: Mathematical and Physical Sciences",

issn = "0080-4630",

publisher = "Royal Society Publishing",

}

TY - JOUR

T1 - Higher order hyperfine terms in the spin Hamiltonian

AU - Golding, R. M.

AU - Stubbs, L. C.

PY - 1978

Y1 - 1978

N2 - The higher order hyperfine terms in the spin Hamiltonian are evaluated for the general case where the hyperfine interaction raises from the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum interactions of a d-electron associated dominantly with one nucleus coupling with another nucleus, where the electronic wavefunction is described by a Slater-type orbital. The method handles long range and short range coupling including the free atom case. The case for a one-electron transition metal ion in a crystal field environment of octahedral symmetry is examined.

AB - The higher order hyperfine terms in the spin Hamiltonian are evaluated for the general case where the hyperfine interaction raises from the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum interactions of a d-electron associated dominantly with one nucleus coupling with another nucleus, where the electronic wavefunction is described by a Slater-type orbital. The method handles long range and short range coupling including the free atom case. The case for a one-electron transition metal ion in a crystal field environment of octahedral symmetry is examined.

U2 - 10.1098/rspa.1978.0148

DO - 10.1098/rspa.1978.0148

M3 - Article

SN - 0080-4630

VL - 362

SP - 525

EP - 536

JO - Proceedings of The Royal Society of London, Series A: Mathematical and Physical Sciences

JF - Proceedings of The Royal Society of London, Series A: Mathematical and Physical Sciences

ER -

Higher order hyperfine terms in the spin Hamiltonian

Abstract

Access to Document

Fingerprint

Cite this