HPLC separation of diastereomeric metal complexes of the form Δ,Λ-[Ru(diimine)2(S)-aminoacidate]

Janice R. Aldrich-Wright*, Robert S. Vagg, Peter A. Williams

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Complete separation of the photosensitive diastereomeric complexes of the general form [Ru(diimine)2(S)-aminoacidate], in which the diimine is 1,10-phenanthroline (phen) or 2,2′-bipyridine (bpy) and (S)-amino or N-methyl-(S)-aminoacidate are (S)-aspartate, (S)-tryptophanate or N-methyl-(S)-tryptophanate, has been achieved by reversed-phase ion-interaction chromatography. This has allowed the photo-equilibrated isomeric ratios for each complex to be estimated.

Original languageEnglish
Pages (from-to)1193-1200
Number of pages8
JournalAustralian Journal of Chemistry
Volume56
Issue number12
DOIs
Publication statusPublished - 2003

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