Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

Samir Barman, Hiroyasu Furukawa*, Olivier Blacque, Koushik Venkatesan, Omar M. Yaghi, Guo Xin Jin, Heinz Berke

*Corresponding author for this work

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

Original languageEnglish
Pages (from-to)11882-11884
Number of pages3
JournalChemical Communications
Volume47
Issue number43
DOIs
Publication statusPublished - 21 Nov 2011
Externally publishedYes

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