Infrared-ultraviolet double resonance studies of fast vibrational energy transfer in D2CO

B. J. Orr; C. P. Bewick

Infrared-ultraviolet double resonance studies of fast vibrational energy transfer in D2CO

B. J. Orr^*, C. P. Bewick

^*Corresponding author for this work

Macquarie University BioFocus Research Centre

Research output: Chapter in Book/Report/Conference proceeding › Conference proceeding contribution › peer-review

Abstract

Experiments are reported showing that collisional V-V transfer between the ν₆ (inplane wag, 989-cm^-1) and ν₄) (out-of-plane bend, 938-cm^-1) vibrational modes is remarkably rapid, occurring with approximately gas-kinetic efficiency. Earlier studies of D₂CO/D₂CO collisions have been extended to a variety of collision partners (He, Ar, CH₄, N₂, N₂O), providing some control of the relative rates of ν₆ → ν₄ transfer and of rotational relaxation with respect to quantum numbers J and K_a. The extraordinary efficiency of collision-induced ν₆ → ν₄ transfer in D₂CO is attributable to the rovibrational mixing effect of Coriolis coupling and the availability of a number of efficient quasielastic relaxation channels.

Original language	English
Title of host publication	CLEO 88 Conf Lasers Electro Opt 1988 Tech Dig Ser Vol 7
Place of Publication	Washington, DC
Publisher	Optical Society of America (OSA)
ISBN (Print)	155752033X
Publication status	Published - 1988

Cite this

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title = "Infrared-ultraviolet double resonance studies of fast vibrational energy transfer in D2CO",

abstract = "Experiments are reported showing that collisional V-V transfer between the ν6 (inplane wag, 989-cm-1) and ν4) (out-of-plane bend, 938-cm-1) vibrational modes is remarkably rapid, occurring with approximately gas-kinetic efficiency. Earlier studies of D2CO/D2CO collisions have been extended to a variety of collision partners (He, Ar, CH4, N2, N2O), providing some control of the relative rates of ν6 → ν4 transfer and of rotational relaxation with respect to quantum numbers J and Ka. The extraordinary efficiency of collision-induced ν6 → ν4 transfer in D2CO is attributable to the rovibrational mixing effect of Coriolis coupling and the availability of a number of efficient quasielastic relaxation channels.",

author = "Orr, {B. J.} and Bewick, {C. P.}",

year = "1988",

language = "English",

isbn = "155752033X",

booktitle = "CLEO 88 Conf Lasers Electro Opt 1988 Tech Dig Ser Vol 7",

publisher = "Optical Society of America (OSA)",

address = "United States",

}

TY - GEN

T1 - Infrared-ultraviolet double resonance studies of fast vibrational energy transfer in D2CO

AU - Orr, B. J.

AU - Bewick, C. P.

PY - 1988

Y1 - 1988

N2 - Experiments are reported showing that collisional V-V transfer between the ν6 (inplane wag, 989-cm-1) and ν4) (out-of-plane bend, 938-cm-1) vibrational modes is remarkably rapid, occurring with approximately gas-kinetic efficiency. Earlier studies of D2CO/D2CO collisions have been extended to a variety of collision partners (He, Ar, CH4, N2, N2O), providing some control of the relative rates of ν6 → ν4 transfer and of rotational relaxation with respect to quantum numbers J and Ka. The extraordinary efficiency of collision-induced ν6 → ν4 transfer in D2CO is attributable to the rovibrational mixing effect of Coriolis coupling and the availability of a number of efficient quasielastic relaxation channels.

AB - Experiments are reported showing that collisional V-V transfer between the ν6 (inplane wag, 989-cm-1) and ν4) (out-of-plane bend, 938-cm-1) vibrational modes is remarkably rapid, occurring with approximately gas-kinetic efficiency. Earlier studies of D2CO/D2CO collisions have been extended to a variety of collision partners (He, Ar, CH4, N2, N2O), providing some control of the relative rates of ν6 → ν4 transfer and of rotational relaxation with respect to quantum numbers J and Ka. The extraordinary efficiency of collision-induced ν6 → ν4 transfer in D2CO is attributable to the rovibrational mixing effect of Coriolis coupling and the availability of a number of efficient quasielastic relaxation channels.

UR - http://www.scopus.com/inward/record.url?scp=18744421482&partnerID=8YFLogxK

M3 - Conference proceeding contribution

AN - SCOPUS:18744421482

SN - 155752033X

BT - CLEO 88 Conf Lasers Electro Opt 1988 Tech Dig Ser Vol 7

PB - Optical Society of America (OSA)

CY - Washington, DC

ER -

Infrared-ultraviolet double resonance studies of fast vibrational energy transfer in D2CO

Abstract

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