Infrared-ultraviolet double-resonance studies of rotational relaxation in D2CO

B. J. Orr*, J. G. Haub, G. F. Nutt, J. L. Steward, O. Vozzo

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

Time-resolved infrared-ultraviolet double-resonance spectroscopy provides a sensitive means of studying collision-induced rotational relaxation rates and mechanisms. Relaxation of the 123,10 rotational state in the v4 = 1 vibrational level of D2CO is found to follow electric-dipole selection rules with rates determined absolutely to be as much as five times gas kinetic.

Original languageEnglish
Pages (from-to)621-625
Number of pages5
JournalChemical Physics Letters
Volume78
Issue number3
DOIs
Publication statusPublished - 15 Mar 1981
Externally publishedYes

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