Infrared-ultraviolet double-resonance studies of rotational relaxation in D2CO

B. J. Orr; J. G. Haub; G. F. Nutt; J. L. Steward; O. Vozzo

doi:10.1016/0009-2614(81)85272-4

Infrared-ultraviolet double-resonance studies of rotational relaxation in D₂CO

B. J. Orr^*, J. G. Haub, G. F. Nutt, J. L. Steward, O. Vozzo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Time-resolved infrared-ultraviolet double-resonance spectroscopy provides a sensitive means of studying collision-induced rotational relaxation rates and mechanisms. Relaxation of the 12_3,10 rotational state in the v₄ = 1 vibrational level of D₂CO is found to follow electric-dipole selection rules with rates determined absolutely to be as much as five times gas kinetic.

Original language	English
Pages (from-to)	621-625
Number of pages	5
Journal	Chemical Physics Letters
Volume	78
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(81)85272-4
Publication status	Published - 15 Mar 1981
Externally published	Yes

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title = "Infrared-ultraviolet double-resonance studies of rotational relaxation in D2CO",

abstract = "Time-resolved infrared-ultraviolet double-resonance spectroscopy provides a sensitive means of studying collision-induced rotational relaxation rates and mechanisms. Relaxation of the 123,10 rotational state in the v4 = 1 vibrational level of D2CO is found to follow electric-dipole selection rules with rates determined absolutely to be as much as five times gas kinetic.",

author = "Orr, {B. J.} and Haub, {J. G.} and Nutt, {G. F.} and Steward, {J. L.} and O. Vozzo",

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AU - Orr, B. J.

AU - Haub, J. G.

AU - Nutt, G. F.

AU - Steward, J. L.

AU - Vozzo, O.

PY - 1981/3/15

Y1 - 1981/3/15

N2 - Time-resolved infrared-ultraviolet double-resonance spectroscopy provides a sensitive means of studying collision-induced rotational relaxation rates and mechanisms. Relaxation of the 123,10 rotational state in the v4 = 1 vibrational level of D2CO is found to follow electric-dipole selection rules with rates determined absolutely to be as much as five times gas kinetic.

AB - Time-resolved infrared-ultraviolet double-resonance spectroscopy provides a sensitive means of studying collision-induced rotational relaxation rates and mechanisms. Relaxation of the 123,10 rotational state in the v4 = 1 vibrational level of D2CO is found to follow electric-dipole selection rules with rates determined absolutely to be as much as five times gas kinetic.

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DO - 10.1016/0009-2614(81)85272-4

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VL - 78

SP - 621

EP - 625

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Infrared-ultraviolet double-resonance studies of rotational relaxation in D₂CO

Abstract

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