Internal rotation in 1, 2-dichloroethane

R. J W Le Fèvre; B. J. Orr

doi:10.1071/CH9641098

Internal rotation in 1, 2-dichloroethane

R. J W Le Fèvre^*, B. J. Orr

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The magnitudes of dipole moment and molar Kerr constant of 1, 2-dichloroethane as solute in carbon tetrachloride, previously recorded by Aroney, Izsak, and Le Fèvre, are discussed in relation to internal rotation in the molecule. The results are found to be consistent with a mixture consisting of 31.3% of gauche-isomer and 68.7 % of trans-isomer. Estimation of the potential energy barriers restricting intramolecular rotation is attempted and the results found to be satisfactory.

Original language	English
Pages (from-to)	1098-1105
Number of pages	8
Journal	Australian Journal of Chemistry
Volume	17
Issue number	10
DOIs	https://doi.org/10.1071/CH9641098
Publication status	Published - 1964
Externally published	Yes

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title = "Internal rotation in 1, 2-dichloroethane",

abstract = "The magnitudes of dipole moment and molar Kerr constant of 1, 2-dichloroethane as solute in carbon tetrachloride, previously recorded by Aroney, Izsak, and Le F{\`e}vre, are discussed in relation to internal rotation in the molecule. The results are found to be consistent with a mixture consisting of 31.3% of gauche-isomer and 68.7 % of trans-isomer. Estimation of the potential energy barriers restricting intramolecular rotation is attempted and the results found to be satisfactory.",

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AB - The magnitudes of dipole moment and molar Kerr constant of 1, 2-dichloroethane as solute in carbon tetrachloride, previously recorded by Aroney, Izsak, and Le Fèvre, are discussed in relation to internal rotation in the molecule. The results are found to be consistent with a mixture consisting of 31.3% of gauche-isomer and 68.7 % of trans-isomer. Estimation of the potential energy barriers restricting intramolecular rotation is attempted and the results found to be satisfactory.

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Internal rotation in 1, 2-dichloroethane

Abstract

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