Investigation in feasibility of Molybdenum as a back contact layer for Silicon based quantum dot solar cells

Ziyun Lin, Ivan Perez-Wurfl, Lingfeng Wu, Xuguang Jia, Tian Zhang, Binesh Puthen-Veettil, Haixiang Zhang, Dawei Di, Gavin Conibeer

Research output: Chapter in Book/Report/Conference proceedingConference proceeding contributionpeer-review

5 Citations (Scopus)

Abstract

A vertical structure with a back contact layer is suggested for silicon quantum dots (Si QDs) solar cells to overcome the current crowding effect arising from the high lateral resistance in the emitter layer of the existing mesa-structured Si QDs solar cells on quartz substrates. Molybdenum (Mo) is widely used as the back contact layer in CIGS solar cells due to its high electrical conductivity, good optical reflectance and chemical stability. This paper will focus on the feasibility of Mo as a back contact layer deposited between a quartz substrate and a sputtered silicon rich oxide (SRO) bilayers structure to obtain a fully vertical Si QDs solar cell. In this structure, the desired previously mentioned electrical and optical properties of the Mo thin film have to be maintained during and after a high temperature annealing process. This high temperature process is unavoidable in this structure as it is required to form the Si QDs. This paper aims to study factors that have impacts on critical properties of the Mo thin films processed in contact with Si and SiO2 at high temperatures. Characterizations including film thickness, microstructure, sheet resistance and optical reflectance measurements are also performed. Furthermore, interfacial properties between the Mo layer and the upper SRO bilayers are investigated.

Original languageEnglish
Title of host publicationPhysics, Simulation, and Photonic Engineering of Photovoltaic Devices II
EditorsAlexandre Freundlich, Jean-Francois Guillemoles
Place of PublicationBellingham, WA
PublisherSPIE
Pages1-7
Number of pages7
ISBN (Print)9780819493897
DOIs
Publication statusPublished - 2013
Externally publishedYes
Event2nd Symposium on Physics, Simulation, and Photonic Engineering of Photovoltaic Devices - San Francisco, CA, United States
Duration: 3 Feb 20137 Feb 2013

Publication series

NameProceedings of SPIE
PublisherSPIE
Volume8620
ISSN (Print)0277-786X

Conference

Conference2nd Symposium on Physics, Simulation, and Photonic Engineering of Photovoltaic Devices
Country/TerritoryUnited States
CitySan Francisco, CA
Period3/02/137/02/13

Keywords

  • Green photonics
  • Si QDs solar cells
  • Molybdenum
  • Back contact layer

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