TY - JOUR
T1 - Iridium(I)-catalysed tandem hydrosilylation-protodesilylation of imines
AU - Field, Leslie D.
AU - Messerle, Barbara A.
AU - Rumble, Sarah L.
PY - 2005/7/11
Y1 - 2005/7/11
N2 - In the presence of alkylsilanes, the cationic IrI complex [{Ir[bis(pyrazol-1-yl)methane](CO)2}BPh4] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldimines and ketimines. Excellent conversions directly to the product amines are achieved rapidly at room temperature in methanol solution.
AB - In the presence of alkylsilanes, the cationic IrI complex [{Ir[bis(pyrazol-1-yl)methane](CO)2}BPh4] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldimines and ketimines. Excellent conversions directly to the product amines are achieved rapidly at room temperature in methanol solution.
UR - http://www.scopus.com/inward/record.url?scp=22544487232&partnerID=8YFLogxK
U2 - 10.1002/ejoc.200500168
DO - 10.1002/ejoc.200500168
M3 - Article
AN - SCOPUS:22544487232
SN - 1434-193X
SP - 2881
EP - 2883
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 14
ER -