Iridium(I)-catalysed tandem hydrosilylation-protodesilylation of imines

Leslie D. Field, Barbara A. Messerle, Sarah L. Rumble

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

In the presence of alkylsilanes, the cationic IrI complex [{Ir[bis(pyrazol-1-yl)methane](CO)2}BPh4] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldimines and ketimines. Excellent conversions directly to the product amines are achieved rapidly at room temperature in methanol solution.

Original languageEnglish
Pages (from-to)2881-2883
Number of pages3
JournalEuropean Journal of Organic Chemistry
Issue number14
DOIs
Publication statusPublished - 11 Jul 2005
Externally publishedYes

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