Jonker-type analysis of small polaron conductors

J. Nell*, B. J. Wood, S. E. Dorris, T. O. Mason

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    20 Citations (Scopus)

    Abstract

    Plots of Seebeck coefficient vs the logarithm of electrical conductivity (Jonker plots) can be used to discriminate small polaron from band-type semiconductivity. Furthermore n-type and p-type small polaron conduction can be discriminated. Examples are drawn from systems exhibiting extensive nonstoichiometry, e.g., CeO2-x and Fe1-xO, systems involving extensive doping, e.g., LaCro3:Sr and Mn3O4: Fe, and systems with extensive solid solubility, e.g., the spinel ferrites. Capabilities and limitations of the analysis are discussed.

    Original languageEnglish
    Pages (from-to)247-254
    Number of pages8
    JournalJournal of Solid State Chemistry
    Volume82
    Issue number2
    DOIs
    Publication statusPublished - 1989

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