Abstract
The kinetics of iso-octane steam reforming over a nickel based catalyst has been examined as a function of iso-octane and steam partial pressures at various temperatures. The reaction order is 0.2 with respect to iso-octane, suggesting strong coverage of nickel by iso-octane and 0.5 with respect to steam, indicating dissociative adsorption of steam. Indeed, a Langmuir-Hinshelwood (LH) mechanism requiring the dissociative adsorption of iso-octane and steam on two different sites appeared to be the most plausible pathway for the steam reforming reaction. The activation energy of 44 ± 2.2 kJ mol-1 estimated from the LH model is consistent with the trend previously reported for other lower hydrocarbons.
Original language | English |
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Pages (from-to) | 131-136 |
Number of pages | 6 |
Journal | Chemical Engineering Journal |
Volume | 99 |
Issue number | 2 |
DOIs | |
Publication status | Published - 15 Jun 2004 |
Keywords
- Gasoline
- Iso-Octane
- Kinetic
- Nickel
- Steam reforming