Kinetics of skeletal rearrangement of H2FeP[CH2CH2CH2P(CH3)2]3 by an inversion–transfer–recovery NMR method

Leslie D. Field*, Nick Bampos, Barbara A. Messerle

*Corresponding author for this work

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The iron dihydride FeH2(PP3) [PP3 = P(CH2CH2CH2PMe2)3] is fluctional, with the terminal co‐ordinated phos‐phine groups undergoing intramolecular exchange in addition to the iron‐bound hydrides. The exchange kinetics of the metal‐bound hydrides was examined using a magnetization inversion–transfer–recovery method, and the activation energy was ca. 64 kJ mol−1 at 260 K. The effect of spin–spin coupling on the magnetization transfer was examined.

Original languageEnglish
Pages (from-to)36-39
Number of pages4
JournalMagnetic Resonance in Chemistry
Volume29
Issue number1
DOIs
Publication statusPublished - 1991
Externally publishedYes

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