Mössbauer studies of ferrous-A zeolite. Part 3.-The adsorption of ethanol

Bruce L. Dickson; Lovat V C Rees

doi:10.1039/F19747002060

Mössbauer studies of ferrous-A zeolite. Part 3.-The adsorption of ethanol

Bruce L. Dickson, Lovat V C Rees^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Mössbauer spectra have been taken after successive additions of small doses of ethanol have been made in dehydrated ferrous-A. These spectra show that two molecules of adsorbate coordinate to each ferrous ion. When the zeolite is saturated with ethanol, ca. 20% of the ferrous ions remain uncomplexed. The restrictions of space in the cages of this zeolite prevent the optimum packing of the adsorbate molecules. The complexes formed with the ferrous ions by water, methanol and ethanol are compared and their differences interpreted.

Original language	English
Pages (from-to)	2060-2065
Number of pages	6
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	70
DOIs	https://doi.org/10.1039/F19747002060
Publication status	Published - 1974

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AB - Mössbauer spectra have been taken after successive additions of small doses of ethanol have been made in dehydrated ferrous-A. These spectra show that two molecules of adsorbate coordinate to each ferrous ion. When the zeolite is saturated with ethanol, ca. 20% of the ferrous ions remain uncomplexed. The restrictions of space in the cages of this zeolite prevent the optimum packing of the adsorbate molecules. The complexes formed with the ferrous ions by water, methanol and ethanol are compared and their differences interpreted.

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ER -

Mössbauer studies of ferrous-A zeolite. Part 3.-The adsorption of ethanol

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