Mössbauer studies of ferrous-A zeolite. Part 3.-The adsorption of ethanol

Bruce L. Dickson, Lovat V C Rees*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    16 Citations (Scopus)

    Abstract

    Mössbauer spectra have been taken after successive additions of small doses of ethanol have been made in dehydrated ferrous-A. These spectra show that two molecules of adsorbate coordinate to each ferrous ion. When the zeolite is saturated with ethanol, ca. 20% of the ferrous ions remain uncomplexed. The restrictions of space in the cages of this zeolite prevent the optimum packing of the adsorbate molecules. The complexes formed with the ferrous ions by water, methanol and ethanol are compared and their differences interpreted.

    Original languageEnglish
    Pages (from-to)2060-2065
    Number of pages6
    JournalJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
    Volume70
    DOIs
    Publication statusPublished - 1974

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