Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Adam D. Martin; Alexandre N. Sobolev; Colin L. Raston

doi:10.1039/c003053h

Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Adam D. Martin, Alexandre N. Sobolev, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

O-Alkylated calix[4]arenes with varying chain lengths, corresponding to C_nH_2n+1 where n = 12, 14 or 16, compounds 1–3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

Original language	English
Pages (from-to)	2666-2668
Number of pages	3
Journal	CrystEngComm
Volume	12
Issue number	10
DOIs	https://doi.org/10.1039/c003053h
Publication status	Published - 2010
Externally published	Yes

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title = "Mapping out the diversity of interplay of O-alkylated calix[4]arenes",

abstract = "O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1–3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.",

author = "Martin, {Adam D.} and Sobolev, {Alexandre N.} and Raston, {Colin L.}",

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T1 - Mapping out the diversity of interplay of O-alkylated calix[4]arenes

AU - Martin, Adam D.

AU - Sobolev, Alexandre N.

AU - Raston, Colin L.

PY - 2010

Y1 - 2010

N2 - O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1–3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

AB - O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1–3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

U2 - 10.1039/c003053h

DO - 10.1039/c003053h

M3 - Article

SN - 1466-8033

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SP - 2666

EP - 2668

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IS - 10

ER -

Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Abstract

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