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Mitigating cryogenic microcracking in carbon-fibre reinforced polymer composites using negative thermal-expansion nanoparticles functionalized by a polydopamine coating

Mohammad S. Islam, Wenkai Chang, Zhao Sha, Jiawei Wang, Shuying Wu, L. R. Francis Rose, Anthony J. Kinloch, Chun H. Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

Herein, we report a new method of mitigating cryogenic microcracking in carbon-fibre reinforced-plastics (CFRPs) using a negative thermal-expansion nanomaterial, zirconium tungstate (ZrW2O8), to simultaneously reduce the thermal residual stresses and enhance the fracture energy of the epoxy matrix of CFRPs. The results show that 1 wt% of added ZrW2O8 nanoparticles functionalized by polydopamine can increase the fracture energy of the matrix material by 140%, reduce the coefficient of thermal expansion by 20% and, more importantly, enhance the interlaminar fracture energy of the resulting CFRP by about 100% at −196 °C. The ZrW2O8-modified matrix has been demonstrated to successfully prevent microcracking at −196 °C in a blocked cross-ply CFRP laminate with a [04/908/04] fibre architecture.

Original languageEnglish
Article number110676
Pages (from-to)1-16
Number of pages16
JournalComposites Part B: Engineering
Volume257
DOIs
Publication statusPublished - 15 May 2023

Bibliographical note

Copyright the Author(s) 2023. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

Keywords

  • Zirconium tungstate nanoparticles
  • Laminate toughening
  • Cryogenic applications
  • Fracture energy
  • Coefficient of thermal expansion

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