Mode-to-mode vibrational energy transfer in D2CO: Evidence of coriolis-enhanced rotational selectivity

J. G. Haub; B. J. Orr

doi:10.1016/0009-2614(84)85692-4

Mode-to-mode vibrational energy transfer in D₂CO: Evidence of coriolis-enhanced rotational selectivity

J. G. Haub^*, B. J. Orr

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Infrared-ultraviolet double resonance spectroscopy is used to demonstrate rapid collision-induced V-V transfer between the v₆ and v₄ vibrational manifolds of D₂CO. The rate of transfer is at least gas-kinetic and is explained in terms of Coriolis coupling and rotationally specific, quasi-resonant relaxation channels.

Original language	English
Pages (from-to)	162-167
Number of pages	6
Journal	Chemical Physics Letters
Volume	107
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(84)85692-4
Publication status	Published - 25 May 1984
Externally published	Yes

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10.1016/0009-2614(84)85692-4

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@article{b520cc3e39c54a758f9522862167bb59,

title = "Mode-to-mode vibrational energy transfer in D2CO: Evidence of coriolis-enhanced rotational selectivity",

abstract = "Infrared-ultraviolet double resonance spectroscopy is used to demonstrate rapid collision-induced V-V transfer between the v6 and v4 vibrational manifolds of D2CO. The rate of transfer is at least gas-kinetic and is explained in terms of Coriolis coupling and rotationally specific, quasi-resonant relaxation channels.",

author = "Haub, {J. G.} and Orr, {B. J.}",

year = "1984",

month = may,

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doi = "10.1016/0009-2614(84)85692-4",

language = "English",

volume = "107",

pages = "162--167",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Mode-to-mode vibrational energy transfer in D2CO

T2 - Evidence of coriolis-enhanced rotational selectivity

AU - Haub, J. G.

AU - Orr, B. J.

PY - 1984/5/25

Y1 - 1984/5/25

N2 - Infrared-ultraviolet double resonance spectroscopy is used to demonstrate rapid collision-induced V-V transfer between the v6 and v4 vibrational manifolds of D2CO. The rate of transfer is at least gas-kinetic and is explained in terms of Coriolis coupling and rotationally specific, quasi-resonant relaxation channels.

AB - Infrared-ultraviolet double resonance spectroscopy is used to demonstrate rapid collision-induced V-V transfer between the v6 and v4 vibrational manifolds of D2CO. The rate of transfer is at least gas-kinetic and is explained in terms of Coriolis coupling and rotationally specific, quasi-resonant relaxation channels.

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U2 - 10.1016/0009-2614(84)85692-4

DO - 10.1016/0009-2614(84)85692-4

M3 - Article

AN - SCOPUS:18844394095

VL - 107

SP - 162

EP - 167

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 2

ER -

Mode-to-mode vibrational energy transfer in D₂CO: Evidence of coriolis-enhanced rotational selectivity

Abstract

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