Molecular polarisability. The conformations of six molecules containing the cyano-group

R. J W Le Fèvre, G. L D Ritchie, P. J. Stiles

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

LanguageEnglish
Pages819-824
Number of pages6
JournalJournal of the Chemical Society B: Physical Organic
DOIs
Publication statusPublished - 1967
Externally publishedYes

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Carbon Tetrachloride
Dipole moment
Benzene
Conformations
solutes
Molecules
carbon tetrachloride
molecules
ethers
dipole moments
benzene
diversifolin methyl ether
3-cyanopropene

Cite this

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title = "Molecular polarisability. The conformations of six molecules containing the cyano-group",
abstract = "Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.",
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year = "1967",
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journal = "Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry",
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}

Molecular polarisability. The conformations of six molecules containing the cyano-group. / Le Fèvre, R. J W; Ritchie, G. L D; Stiles, P. J.

In: Journal of the Chemical Society B: Physical Organic, 1967, p. 819-824.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Molecular polarisability. The conformations of six molecules containing the cyano-group

AU - Le Fèvre, R. J W

AU - Ritchie, G. L D

AU - Stiles, P. J.

PY - 1967

Y1 - 1967

N2 - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

AB - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

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