TY - JOUR
T1 - Molecular polarisability. The conformations of six molecules containing the cyano-group
AU - Le Fèvre, R. J W
AU - Ritchie, G. L D
AU - Stiles, P. J.
PY - 1967
Y1 - 1967
N2 - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.
AB - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.
UR - http://www.scopus.com/inward/record.url?scp=37049130266&partnerID=8YFLogxK
U2 - 10.1039/J29670000819
DO - 10.1039/J29670000819
M3 - Article
AN - SCOPUS:37049130266
SP - 819
EP - 824
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9234
ER -