Molecular polarisability. The conformations of six molecules containing the cyano-group

R. J W Le Fèvre; G. L D Ritchie; P. J. Stiles

doi:10.1039/J29670000819

Molecular polarisability. The conformations of six molecules containing the cyano-group

R. J W Le Fèvre^*, G. L D Ritchie, P. J. Stiles

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Dipole moments and molar Kerr constants (×10¹²) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

Original language	English
Pages (from-to)	819-824
Number of pages	6
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/J29670000819
Publication status	Published - 1967
Externally published	Yes

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title = "Molecular polarisability. The conformations of six molecules containing the cyano-group",

abstract = "Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.",

author = "\{Le F{\`e}vre\}, \{R. J W\} and Ritchie, \{G. L D\} and Stiles, \{P. J.\}",

year = "1967",

doi = "10.1039/J29670000819",

language = "English",

pages = "819--824",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Molecular polarisability. The conformations of six molecules containing the cyano-group

AU - Le Fèvre, R. J W

AU - Ritchie, G. L D

AU - Stiles, P. J.

PY - 1967

Y1 - 1967

N2 - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

AB - Dipole moments and molar Kerr constants (×1012) at 25° are reported for cyanomethyl methyl ether (2.99 D, +111) 1-cyanopropane (3.53 D, +281), 1-cyano-2-methylpropane (3.62 D, +256), 3-cyanopropene (3.48 D, +263), and diphenylcyanomethane (3.57 D, -18) as solutes in carbon tetrachloride, together with the molar Kerr constant of 1,2-dicyanoethane (+21) as a solute in benzene. Conformations of the molecules are investigated. The possibility of solvent-induced conformational changes of 1,2-dicyanoethane is discussed.

UR - https://www.scopus.com/pages/publications/37049130266

U2 - 10.1039/J29670000819

DO - 10.1039/J29670000819

M3 - Article

AN - SCOPUS:37049130266

SN - 1477-9226

SP - 819

EP - 824

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Molecular polarisability. The conformations of six molecules containing the cyano-group

Abstract

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