Monitoring steel bridge renovation using lead isotopic tracing

Fred Salome, Brian Gulson*, Massimo Chiaradia, Jeffrey Davis, Howard Morris

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    1 Citation (Scopus)

    Abstract

    Monitoring removal of lead (Pb) paint from steel structures usually involves analysis of environmental samples for total lead and determination of blood Pb levels of employees involved in the Pb paint removal. We used high precision Pb isotopic tracing for a bridge undergoing Pb paint removal to determine if Pb in the environmental and blood samples originated from the bridge paint. The paint system on the bridge consisted of an anti-corrosive red Pb primer top-coated with a Micaceous Iron Oxide (MIO) alkyd. Analysis of the red Pb primer gave uniform isotopic ratios indicative of Pb from the geologically-ancient Broken Hill mines in western New South Wales, Australia. Likewise waste abrasive material, as anticipated, had the same isotopic composition as the paint. The isotopic ratios for other samples lay on 2 separate linear arrays on a207Pb/204Pb versus 206Pb/204Pb diagram, one largely defined by gasoline and the majority of the ambient air data, and the other by data for one sample each of gasoline and ambient air and underwater sediments. Isotopic ratios in background ambient air samples for the project were characteristic of leaded gasoline. Air sampling during paint removal showed a contribution of paint Pb ranging from about 20 to 40%. Isotopic ratios in the blood of 8 employees prior to the commencement of work showed that 6 of these had been previously exposed to the Broken Hill Pb possibly from earlier bridge paint removal projects. One subject appeared to have increased exposure to Pb probably from the paint renovations.

    Original languageEnglish
    Pages (from-to)260-267
    Number of pages8
    JournalChemosphere
    Volume174
    DOIs
    Publication statusPublished - May 2017

    Keywords

    • Bridge paint
    • Air sampling
    • Water sediments
    • Gasoline
    • Blood
    • Lead isotopes

    Fingerprint Dive into the research topics of 'Monitoring steel bridge renovation using lead isotopic tracing'. Together they form a unique fingerprint.

    Cite this