Mononuclear rhodium(I) complexes with chelating N-heterocyclic carbene ligands - Catalytic activity for intramolecular hydroamination

Suzanne Burling; Leslie D. Field; Hsiu L. Li; Barbara A. Messerle; Peter Turner

Mononuclear rhodium(I) complexes with chelating N-heterocyclic carbene ligands - Catalytic activity for intramolecular hydroamination

Suzanne Burling, Leslie D. Field, Hsiu L. Li, Barbara A. Messerle, Peter Turner

Faculty of Science and Engineering

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

The mononuclear cationic Rh^I complexes [Rh(cod)(mdd)] ⁺X^- and [Rh(CO)₂(mdd)]⁺X ^- (X = BPh₄, PF₆) containing the chelating bidentate N-heterocyclic carbene ligand 1,1′-methylene - 3,3′-dimethyldiimidazoline-2,2′-diylidene (mdd) have been synthesised and spectroscopically characterised. The complexes [Rh(cod)(mdd)]⁺BPh₄ ^- and [Rh(CO) ₂(mdd)]⁺PF₆ ^- have also been characterised by X-ray crystallography. The dicarbonyl complexes catalyse the intramolecular hydroamination of 4-pentyn-1-amine to 2-methyl-1-pyrroline. (

Original language	English
Pages (from-to)	3179-3184
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	17
Publication status	Published - 5 Sept 2003

Cite this

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title = "Mononuclear rhodium(I) complexes with chelating N-heterocyclic carbene ligands - Catalytic activity for intramolecular hydroamination",

abstract = "The mononuclear cationic RhI complexes [Rh(cod)(mdd)] +X- and [Rh(CO)2(mdd)]+X - (X = BPh4, PF6) containing the chelating bidentate N-heterocyclic carbene ligand 1,1′-methylene - 3,3′-dimethyldiimidazoline-2,2′-diylidene (mdd) have been synthesised and spectroscopically characterised. The complexes [Rh(cod)(mdd)]+BPh4 - and [Rh(CO) 2(mdd)]+PF6 - have also been characterised by X-ray crystallography. The dicarbonyl complexes catalyse the intramolecular hydroamination of 4-pentyn-1-amine to 2-methyl-1-pyrroline. (",

author = "Suzanne Burling and Field, {Leslie D.} and Li, {Hsiu L.} and Messerle, {Barbara A.} and Peter Turner",

year = "2003",

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pages = "3179--3184",

journal = "European Journal of Inorganic Chemistry",

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T1 - Mononuclear rhodium(I) complexes with chelating N-heterocyclic carbene ligands - Catalytic activity for intramolecular hydroamination

AU - Burling, Suzanne

AU - Field, Leslie D.

AU - Li, Hsiu L.

AU - Messerle, Barbara A.

AU - Turner, Peter

PY - 2003/9/5

Y1 - 2003/9/5

N2 - The mononuclear cationic RhI complexes [Rh(cod)(mdd)] +X- and [Rh(CO)2(mdd)]+X - (X = BPh4, PF6) containing the chelating bidentate N-heterocyclic carbene ligand 1,1′-methylene - 3,3′-dimethyldiimidazoline-2,2′-diylidene (mdd) have been synthesised and spectroscopically characterised. The complexes [Rh(cod)(mdd)]+BPh4 - and [Rh(CO) 2(mdd)]+PF6 - have also been characterised by X-ray crystallography. The dicarbonyl complexes catalyse the intramolecular hydroamination of 4-pentyn-1-amine to 2-methyl-1-pyrroline. (

AB - The mononuclear cationic RhI complexes [Rh(cod)(mdd)] +X- and [Rh(CO)2(mdd)]+X - (X = BPh4, PF6) containing the chelating bidentate N-heterocyclic carbene ligand 1,1′-methylene - 3,3′-dimethyldiimidazoline-2,2′-diylidene (mdd) have been synthesised and spectroscopically characterised. The complexes [Rh(cod)(mdd)]+BPh4 - and [Rh(CO) 2(mdd)]+PF6 - have also been characterised by X-ray crystallography. The dicarbonyl complexes catalyse the intramolecular hydroamination of 4-pentyn-1-amine to 2-methyl-1-pyrroline. (

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M3 - Article

AN - SCOPUS:0141704190

SN - 1434-1948

SP - 3179

EP - 3184

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 17

ER -

Mononuclear rhodium(I) complexes with chelating N-heterocyclic carbene ligands - Catalytic activity for intramolecular hydroamination

Abstract

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