Abstract
We report on local photo-induced oxidation of porous silicon in water at room temperature. Starting from a nonluminescent sample, the oxidation process induces luminescence which was found to first increase and then decrease as a function of the oxidation time. A clear blue shift is also observed. This effect is believed to be owing to size modification of silicon nanocrystallites and thus is explained in terms of quantum confinement. Optical near-field images and spectrum are used to monitor the photoluminescence modifications after oxidation. As the photoluminescence can be widely tuned in wavelength and intensity, this method offers a way to pattern the emission properties of the sample.
Original language | English |
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Pages (from-to) | 469-474 |
Number of pages | 6 |
Journal | Journal of Microscopy |
Volume | 229 |
Issue number | 3 |
DOIs | |
Publication status | Published - Mar 2008 |
Keywords
- Oxidation
- Porous silicon
- SNOM