NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

Christopher J. Sleigh, Simon B. Duckett*, Barbara A. Messerle

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH2Cl-(CO)(PPh3)2] and [IrH2Cl(PPh3)3]: these complexes undergo ligand exchange via a 16-electron complex, [IrH2Cl(PPh3)2], which has a square-based pyramidal structure.

Original languageEnglish
Pages (from-to)2395-2396
Number of pages2
JournalChemical Communications
Issue number21
Publication statusPublished - 1996
Externally publishedYes

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