NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

Christopher J. Sleigh; Simon B. Duckett; Barbara A. Messerle

NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

Christopher J. Sleigh, Simon B. Duckett^*, Barbara A. Messerle

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH₂Cl-(CO)(PPh₃)₂] and [IrH₂Cl(PPh₃)₃]: these complexes undergo ligand exchange via a 16-electron complex, [IrH₂Cl(PPh₃)₂], which has a square-based pyramidal structure.

Original language	English
Pages (from-to)	2395-2396
Number of pages	2
Journal	Chemical Communications
Issue number	21
Publication status	Published - 1996
Externally published	Yes

Cite this

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title = "NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation",

abstract = "Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH2Cl-(CO)(PPh3)2] and [IrH2Cl(PPh3)3]: these complexes undergo ligand exchange via a 16-electron complex, [IrH2Cl(PPh3)2], which has a square-based pyramidal structure.",

author = "Sleigh, {Christopher J.} and Duckett, {Simon B.} and Messerle, {Barbara A.}",

year = "1996",

language = "English",

pages = "2395--2396",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

AU - Sleigh, Christopher J.

AU - Duckett, Simon B.

AU - Messerle, Barbara A.

PY - 1996

Y1 - 1996

N2 - Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH2Cl-(CO)(PPh3)2] and [IrH2Cl(PPh3)3]: these complexes undergo ligand exchange via a 16-electron complex, [IrH2Cl(PPh3)2], which has a square-based pyramidal structure.

AB - Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH2Cl-(CO)(PPh3)2] and [IrH2Cl(PPh3)3]: these complexes undergo ligand exchange via a 16-electron complex, [IrH2Cl(PPh3)2], which has a square-based pyramidal structure.

UR - http://www.scopus.com/inward/record.url?scp=0002804571&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0002804571

SP - 2395

EP - 2396

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 21

ER -

NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

Abstract

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