Novel one-pot synthesis of thiophenols from related triazenes under mild conditions

Ardeshir Khazaei, Masoud Kazem-Rostami*, Ahmadreza Moosavi-Zare, Mohammad Bayat, Shahnaz Saednia

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

In this work, at first, triazenes were synthesized from primary aryl amines. Afterwards, triazenes were converted into the corresponding thiophenols in one-pot using sodium sulfide in acidic media, by in situ generation of diazonium counterion beside hydrogen sulfide as anionic sulfur nucleophile at room temperature. The procedure can be a convenient shortcut for the preparation of thiophenols from primary aryl amines.

Original languageEnglish
Pages (from-to)1893-1896
Number of pages4
JournalSynlett
Volume23
Issue number13
DOIs
Publication statusPublished - 2012
Externally publishedYes

Keywords

  • aryl amine
  • diazonium salt
  • one-pot synthesis
  • thiophenol
  • triazene

Fingerprint

Dive into the research topics of 'Novel one-pot synthesis of thiophenols from related triazenes under mild conditions'. Together they form a unique fingerprint.

Cite this