Nuclear acylation of arylamines

B. Staskun*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    34 Citations (Scopus)

    Abstract

    Aromatic carboxylic acids react with arylamines in polyphosphoric acid solution at 180-200° to furnish aminobenzophenones in appreciable yield. Diphenylamine, triphenylamine, and 2-aminobiphenyl yield heterocyclic bases. Substituted benzanilides are converted to aminobenzophenones by the hot reagent. Mechanisms to account for the results are proposed.

    Original languageEnglish
    Pages (from-to)2856-2860
    Number of pages5
    JournalJournal of Organic Chemistry
    Volume29
    Issue number10
    Publication statusPublished - 1964

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