Nuclear acylation of arylamines

B. Staskun*

*Corresponding author for this work

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Aromatic carboxylic acids react with arylamines in polyphosphoric acid solution at 180-200° to furnish aminobenzophenones in appreciable yield. Diphenylamine, triphenylamine, and 2-aminobiphenyl yield heterocyclic bases. Substituted benzanilides are converted to aminobenzophenones by the hot reagent. Mechanisms to account for the results are proposed.

Original languageEnglish
Pages (from-to)2856-2860
Number of pages5
JournalJournal of Organic Chemistry
Volume29
Issue number10
Publication statusPublished - 1964

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    Staskun, B. (1964). Nuclear acylation of arylamines. Journal of Organic Chemistry, 29(10), 2856-2860.