One-pot synthesis of TBTA-functionalized coordinating polymers

Alireza Movahedi; Kasper Moth-Poulsen; Johnas Eklöf; Magnus Nydén; Nina Kann

doi:10.1016/j.reactfunctpolym.2014.05.008

One-pot synthesis of TBTA-functionalized coordinating polymers

Alireza Movahedi, Kasper Moth-Poulsen, Johnas Eklöf, Magnus Nydén^*, Nina Kann

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

9 Downloads (Pure)

Abstract

A one-pot method for the functionalization of polyvinylbenzyl chloride with a tris-(benzyltriazolylmethyl)amine (TBTA) ligand via the copper-catalyzed azide-alkyne cycloaddition reaction (CuAAC) is reported, where the ligand is constructed simultaneously with its attachment to the polymer backbone. A hydrophobic TBTA polymer as well as co-polymers containing TBTA ligands were also prepared to demonstrate the possibility of tailoring the properties of the polymers. The polymers were characterized with FT-IR and NMR spectroscopy, elemental analysis, contact angle measurement, differential scanning calorimetry and thermal gravimetric analysis. The metal coordinating properties of films prepared from the polymers was also demonstrated using X-ray photoelectron spectroscopy and their structures inspected by scanning electron microscopy.

Original language	English
Pages (from-to)	1-8
Number of pages	8
Journal	Reactive and Functional Polymers
Volume	82
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2014.05.008
Publication status	Published - Sept 2014
Externally published	Yes

Bibliographical note

Copyright the Author(s) 2014. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

Keywords

Polyvinylbenzyl chloride
Cycloaddition
Triazole
Coordinating polymer
Copper

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10.1016/j.reactfunctpolym.2014.05.008Licence: CC BY-NC-ND

Publisher version (open access)Final published version, 1.12 MBLicence: CC BY-NC-ND

Cite this

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title = "One-pot synthesis of TBTA-functionalized coordinating polymers",

abstract = "A one-pot method for the functionalization of polyvinylbenzyl chloride with a tris-(benzyltriazolylmethyl)amine (TBTA) ligand via the copper-catalyzed azide-alkyne cycloaddition reaction (CuAAC) is reported, where the ligand is constructed simultaneously with its attachment to the polymer backbone. A hydrophobic TBTA polymer as well as co-polymers containing TBTA ligands were also prepared to demonstrate the possibility of tailoring the properties of the polymers. The polymers were characterized with FT-IR and NMR spectroscopy, elemental analysis, contact angle measurement, differential scanning calorimetry and thermal gravimetric analysis. The metal coordinating properties of films prepared from the polymers was also demonstrated using X-ray photoelectron spectroscopy and their structures inspected by scanning electron microscopy.",

keywords = "Polyvinylbenzyl chloride, Cycloaddition, Triazole, Coordinating polymer, Copper",

author = "Alireza Movahedi and Kasper Moth-Poulsen and Johnas Ekl{\"o}f and Magnus Nyd{\'e}n and Nina Kann",

note = "Copyright the Author(s) 2014. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.",

year = "2014",

month = sep,

doi = "10.1016/j.reactfunctpolym.2014.05.008",

language = "English",

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T1 - One-pot synthesis of TBTA-functionalized coordinating polymers

AU - Movahedi, Alireza

AU - Moth-Poulsen, Kasper

AU - Eklöf, Johnas

AU - Nydén, Magnus

AU - Kann, Nina

N1 - Copyright the Author(s) 2014. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

PY - 2014/9

Y1 - 2014/9

N2 - A one-pot method for the functionalization of polyvinylbenzyl chloride with a tris-(benzyltriazolylmethyl)amine (TBTA) ligand via the copper-catalyzed azide-alkyne cycloaddition reaction (CuAAC) is reported, where the ligand is constructed simultaneously with its attachment to the polymer backbone. A hydrophobic TBTA polymer as well as co-polymers containing TBTA ligands were also prepared to demonstrate the possibility of tailoring the properties of the polymers. The polymers were characterized with FT-IR and NMR spectroscopy, elemental analysis, contact angle measurement, differential scanning calorimetry and thermal gravimetric analysis. The metal coordinating properties of films prepared from the polymers was also demonstrated using X-ray photoelectron spectroscopy and their structures inspected by scanning electron microscopy.

AB - A one-pot method for the functionalization of polyvinylbenzyl chloride with a tris-(benzyltriazolylmethyl)amine (TBTA) ligand via the copper-catalyzed azide-alkyne cycloaddition reaction (CuAAC) is reported, where the ligand is constructed simultaneously with its attachment to the polymer backbone. A hydrophobic TBTA polymer as well as co-polymers containing TBTA ligands were also prepared to demonstrate the possibility of tailoring the properties of the polymers. The polymers were characterized with FT-IR and NMR spectroscopy, elemental analysis, contact angle measurement, differential scanning calorimetry and thermal gravimetric analysis. The metal coordinating properties of films prepared from the polymers was also demonstrated using X-ray photoelectron spectroscopy and their structures inspected by scanning electron microscopy.

KW - Polyvinylbenzyl chloride

KW - Cycloaddition

KW - Triazole

KW - Coordinating polymer

KW - Copper

UR - https://www.scopus.com/pages/publications/84902150614

U2 - 10.1016/j.reactfunctpolym.2014.05.008

DO - 10.1016/j.reactfunctpolym.2014.05.008

M3 - Article

AN - SCOPUS:84902150614

SN - 1381-5148

VL - 82

SP - 1

EP - 8

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

ER -

One-pot synthesis of TBTA-functionalized coordinating polymers

Abstract

Bibliographical note

Keywords

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