Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes

Minoo Dabiri; Neda Salarinejad; Siyavash Kazemi Movahed; Moein Keshmiri; Sahareh Bashiribod

doi:10.1016/j.ica.2023.121631

Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes

Minoo Dabiri^*, Neda Salarinejad, Siyavash Kazemi Movahed^*, Moein Keshmiri, Sahareh Bashiribod

^*Corresponding author for this work

School of Natural Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Fe₃O₄ nanospindles were synthesized through the hydrothermal method followed by thermal treatment. The composite of Fe₃O₄@SiO₂ core–shell nanospindles was synthesized by the Stuber process via the hydrolysis of tetraethyl orthosilicate (TEOS) in the presence of Fe₃O₄ nanospindles. Palladium triazine‐bridged bisimidazolium pincer complex was successfully supported on Fe₃O₄@SiO₂ core–shell nanospindles. The magnetic nanospindles‐supported palladium CNC-pincer complex was used as a practical and recyclable catalyst in the Mizoroki–Heck cross-coupling reaction and reduction of nitroarenes.

Original language	English
Article number	121631
Pages (from-to)	1-12
Number of pages	12
Journal	Inorganica Chimica Acta
Volume	556
Early online date	12 Jun 2023
DOIs	https://doi.org/10.1016/j.ica.2023.121631
Publication status	Published - 1 Oct 2023

Keywords

Core-shell
Magnetic
Nanostructure
Palladium
Pincer

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10.1016/j.ica.2023.121631

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@article{46b06d0535684f3f85430352106b5083,

title = "Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes",

abstract = "Fe3O4 nanospindles were synthesized through the hydrothermal method followed by thermal treatment. The composite of Fe3O4@SiO2 core–shell nanospindles was synthesized by the Stuber process via the hydrolysis of tetraethyl orthosilicate (TEOS) in the presence of Fe3O4 nanospindles. Palladium triazine‐bridged bisimidazolium pincer complex was successfully supported on Fe3O4@SiO2 core–shell nanospindles. The magnetic nanospindles‐supported palladium CNC-pincer complex was used as a practical and recyclable catalyst in the Mizoroki–Heck cross-coupling reaction and reduction of nitroarenes.",

keywords = "Core-shell, Magnetic, Nanostructure, Palladium, Pincer",

author = "Minoo Dabiri and Neda Salarinejad and \{Kazemi Movahed\}, Siyavash and Moein Keshmiri and Sahareh Bashiribod",

year = "2023",

month = oct,

day = "1",

doi = "10.1016/j.ica.2023.121631",

language = "English",

volume = "556",

pages = "1--12",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes. / Dabiri, Minoo; Salarinejad, Neda; Kazemi Movahed, Siyavash et al.
In: Inorganica Chimica Acta, Vol. 556, 121631, 01.10.2023, p. 1-12.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes

AU - Dabiri, Minoo

AU - Salarinejad, Neda

AU - Kazemi Movahed, Siyavash

AU - Keshmiri, Moein

AU - Bashiribod, Sahareh

PY - 2023/10/1

Y1 - 2023/10/1

N2 - Fe3O4 nanospindles were synthesized through the hydrothermal method followed by thermal treatment. The composite of Fe3O4@SiO2 core–shell nanospindles was synthesized by the Stuber process via the hydrolysis of tetraethyl orthosilicate (TEOS) in the presence of Fe3O4 nanospindles. Palladium triazine‐bridged bisimidazolium pincer complex was successfully supported on Fe3O4@SiO2 core–shell nanospindles. The magnetic nanospindles‐supported palladium CNC-pincer complex was used as a practical and recyclable catalyst in the Mizoroki–Heck cross-coupling reaction and reduction of nitroarenes.

AB - Fe3O4 nanospindles were synthesized through the hydrothermal method followed by thermal treatment. The composite of Fe3O4@SiO2 core–shell nanospindles was synthesized by the Stuber process via the hydrolysis of tetraethyl orthosilicate (TEOS) in the presence of Fe3O4 nanospindles. Palladium triazine‐bridged bisimidazolium pincer complex was successfully supported on Fe3O4@SiO2 core–shell nanospindles. The magnetic nanospindles‐supported palladium CNC-pincer complex was used as a practical and recyclable catalyst in the Mizoroki–Heck cross-coupling reaction and reduction of nitroarenes.

KW - Core-shell

KW - Magnetic

KW - Nanostructure

KW - Palladium

KW - Pincer

UR - https://www.scopus.com/pages/publications/85162140204

U2 - 10.1016/j.ica.2023.121631

DO - 10.1016/j.ica.2023.121631

M3 - Article

AN - SCOPUS:85162140204

SN - 0020-1693

VL - 556

SP - 1

EP - 12

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 121631

ER -

Palladium CNC-pincer complex supported on magnetic nanospindles as a highly efficient and recyclable nanocatalyst in Mizoroki–Heck cross-coupling and reduction of nitroarenes

Abstract

Keywords

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