TY - JOUR
T1 - Photobleaching dynamics in small molecule vs. polymer organic photovoltaic blends with 1,7-bis-trifluoromethylfullerene
AU - Garner, Logan E.
AU - Nellissery Viswanathan, Vinila
AU - Arias, Dylan H.
AU - Brook, Colin P.
AU - Christensen, Steven T.
AU - Ferguson, Andrew J.
AU - Kopidakis, Nikos
AU - Larson, Bryon W.
AU - Owczarczyk, Zbyslaw R.
AU - Pfeilsticker, Jason R.
AU - Ramamurthy, Praveen C.
AU - Strauss, Steven H.
AU - Boltalina, Olga V.
AU - Braunecker, Wade A.
PY - 2018
Y1 - 2018
N2 - Two organic photovoltaic (OPV) donor materials (one polymer and one small molecule) are synthesized from the same constituent building blocks, namely thiophene units, cyclopentathiophene dione (CTD), and cyclopentadithiophene (CPDT). Photobleaching dynamics of these donor materials are then studied under white light illumination in air with blends of PC70BM and the bis-trifluoromethylfullerene 1,7-C60(CF3)2. For both the polymer and small molecule blends, C60(CF3)2 stabilizes the initial rate of photobleaching by a factor of 15 relative to PC70BM. However, once the small molecule:C60(CF3)2 blend bleaches to ∼80% of its initial optical density, the rate of photobleaching dramatically accelerates, which is not observed in the analogous polymer blend. We probe that phenomenon using time-resolved photoluminescence (TRPL) to measure PL quenching efficiencies at defined intervals during the photobleaching experiments. The data indicates the small molecule donor and C60(CF3)2 acceptor significantly de-mix with time, after which the blend begins to bleach at approximately the same rate as the neat donor sample. The work suggests that perfluoroalkylfullerenes have great potential to stabilize certain OPV active layers toward photodegradation, provided their morphology is stable.
AB - Two organic photovoltaic (OPV) donor materials (one polymer and one small molecule) are synthesized from the same constituent building blocks, namely thiophene units, cyclopentathiophene dione (CTD), and cyclopentadithiophene (CPDT). Photobleaching dynamics of these donor materials are then studied under white light illumination in air with blends of PC70BM and the bis-trifluoromethylfullerene 1,7-C60(CF3)2. For both the polymer and small molecule blends, C60(CF3)2 stabilizes the initial rate of photobleaching by a factor of 15 relative to PC70BM. However, once the small molecule:C60(CF3)2 blend bleaches to ∼80% of its initial optical density, the rate of photobleaching dramatically accelerates, which is not observed in the analogous polymer blend. We probe that phenomenon using time-resolved photoluminescence (TRPL) to measure PL quenching efficiencies at defined intervals during the photobleaching experiments. The data indicates the small molecule donor and C60(CF3)2 acceptor significantly de-mix with time, after which the blend begins to bleach at approximately the same rate as the neat donor sample. The work suggests that perfluoroalkylfullerenes have great potential to stabilize certain OPV active layers toward photodegradation, provided their morphology is stable.
UR - http://www.scopus.com/inward/record.url?scp=85043766135&partnerID=8YFLogxK
U2 - 10.1039/c7ta10995d
DO - 10.1039/c7ta10995d
M3 - Article
AN - SCOPUS:85043766135
SN - 2050-7488
VL - 6
SP - 4623
EP - 4628
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 11
ER -