Photochemical upconversion of near-infrared light from below the silicon bandgap

Elham M. Gholizadeh, Shyamal K. K. Prasad, Zhi Li Teh, Thilini Ishwara, Sarah Norman, Anthony J. Petty II, Jared H. Cole, Soshan Cheong, Richard D. Tilley, John E. Anthony, Shujuan Huang, Timothy W. Schmidt*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Photochemical upconversion is a strategy for converting infrared light into more energetic, visible light, with potential applications ranging from biological imaging and drug delivery to photovoltaics and photocatalysis. Although systems have been developed for upconverting light from photon energies in the near-infrared, upconversion from below the silicon bandgap has been out of reach. Here, we demonstrate an upconversion composition using PbS semiconductor nanocrystal sensitizers that absorb photons below the bandgap of silicon and populate violanthrone triplet states below the singlet oxygen energy. The triplet-state violanthrone chromophores luminesce in the visible spectrum following energy delivery from two singlet oxygen molecules. By incorporating organic chromophores as ligands onto the PbS nanocrystals to improve energy transfer, we demonstrate that violanthrone upconverts in the absence of oxygen by the triplet–triplet annihilation mechanism. The change in mechanism is shown by exploiting the magnetic field effect on triplet–triplet interactions.

Original languageEnglish
Pages (from-to)585-590
Number of pages7
JournalNature Photonics
Volume14
DOIs
Publication statusPublished - Sep 2020
Externally publishedYes

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