TY - JOUR
T1 - Porphyrin analogues of Tröger's base
T2 - Large chiral cavities with a bimetallic binding site
AU - Crossley, Maxwell J.
AU - Hambley, Trevor W.
AU - MacKay, Lindsey G.
AU - Try, Andrew C.
AU - Walton, Robin
PY - 1995
Y1 - 1995
N2 - 2-Amino-5,10,15,20-tetraarylporphyrins react with formaldehyde to give good yields of the corresponding octaaryl derivatives of the Tröger's base analogue in which two porphyrins are covalently linked by a diazocine bridge; the X-ray crystal-structure of the bis(tetraphenylporphyrinato)dipalladium(II) derivative 6 reveals a concave chiral cavity with two metal ion binding sites suitable for ditopic interactions with guest molecules.
AB - 2-Amino-5,10,15,20-tetraarylporphyrins react with formaldehyde to give good yields of the corresponding octaaryl derivatives of the Tröger's base analogue in which two porphyrins are covalently linked by a diazocine bridge; the X-ray crystal-structure of the bis(tetraphenylporphyrinato)dipalladium(II) derivative 6 reveals a concave chiral cavity with two metal ion binding sites suitable for ditopic interactions with guest molecules.
UR - http://www.scopus.com/inward/record.url?scp=37049087101&partnerID=8YFLogxK
U2 - 10.1039/C39950001077
DO - 10.1039/C39950001077
M3 - Article
AN - SCOPUS:37049087101
SN - 0022-4936
SP - 1077
EP - 1079
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 10
ER -