Potash-rich volcanic rocks and lamprophyres in western Shandong Province: ⁴⁰Ar-³⁹Ar dating and source tracing

Highly precise ⁴⁰Ar-³⁹Ar dating results demonstrate that the ages of potash-rich volcanic rocks in western Shandong Province are 114.7 - 124.3 Ma, and that of the lamprophyres is 119.6 Ma. The potash-rich volcanic rocks have relatively high(⁸⁷Sr/⁸⁶Sr)_i ratios (0.708715 - 0.711418) and distinctly negative ε_Nd values (-11.47 - -17.54), and are enriched in radiogenic lead (²⁰⁶ Pb/²⁰⁴Pb=17.341-17.622, ²⁰⁷Pb/²⁰⁴Pb=15.525-15.538, ²⁰⁸Pb/²⁰⁴Pb = 37.563-37.684). Similarly, the lamprophyres also have quite low ε_Nd values (-11.57 - -19.64). Based on the fact that the Sr, Nd and Pb isotopic compositions of potash-rich volcanic rocks are very consistent with that of the clinopyroxene separates, and by integrating comprehensive analyses of their tectonic settings, and extensive comparisons of the Sr, Nd isotopic compositions with that of the related simultaneous rocks, it is concluded that the potash-rich volcanic rocks and lamprophyres in western Shandong Province were most possibly derived from the partial melting of enriched mantle which was caused by source contamination and metasomatism of subducted continental crustal materials.