Production of oriented nitrogen-vacancy color centers in synthetic diamond

A. M. Edmonds*, U. F S D'Haenens-Johansson, R. J. Cruddace, M. E. Newton, K. M C Fu, C. Santori, R. G. Beausoleil, D. J. Twitchen, M. L. Markham

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

95 Citations (Scopus)


The negatively charged nitrogen-vacancy (NV -) center in diamond is an attractive candidate for applications that range from magnetometry to quantum information processing. Here we show that only a fraction of the nitrogen (typically <0.5%) incorporated during homoepitaxial diamond growth by chemical vapor deposition (CVD) is in the form of undecorated NV - centers. Furthermore, studies on CVD diamond grown on (110)-oriented substrates show a near 100% preferential orientation of NV centers along only the [111] and [1̄1̄1] directions, rather than the four possible orientations. The results indicate that NV centers grow in as units, as the diamond is deposited, rather than by migration and association of their components. The NV unit of the NVH - is similarly preferentially oriented, but it is not possible to determine whether this defect was formed by H capture at a preferentially aligned NV center or as a complete unit. Reducing the number of NV orientations from four orientations to two orientations should lead to increased optically detected magnetic resonance contrast and thus improved magnetic sensitivity in ensemble-based magnetometry.

Original languageEnglish
Article number035201
Pages (from-to)1-7
Number of pages7
JournalPhysical Review B: Condensed Matter and Materials Physics
Issue number3
Publication statusPublished - 5 Jul 2012


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