Reactive (fusible) inertinite in pulverized fuel combustion. 1. A laser microreactor technique

Chris G. Thomas*, Michio Shibaoka, Elizabeth Gawronski, Martin E. Gosnell, Lee F. Brunckhorst, Dheera Phong-anant

*Corresponding author for this work

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The adoption of the concept of reactive (fusible) and inert (infusible) macerals in pulverized fuel (p.f.) combustion is examined together with the need to determine these constituents under realistic conditions. A laser microreactor method is described in which 100 μm monomaceral particles are heated at 105 - 106 K s -1 to ~1600 °C in air. Two applications are described. First, the particles are heated for ~40 ms, the pyrolysis converting the maceral into a char particle with individual morphology; in particular, whether the maceral fuses or melts (termed reactive) or not (termed inert) is determined by optical microscopy. Second, high-speed cinephotomicroscopy of the combusting particle is possible using longer irradiation periods, revealing in great detail the morphology of swelling and combustion. The validity of the method is substantiated by comparing char morphologies with those from a drop-tube furnace. Other features of the laser microreactor technique are discussed and it is shown that the equipment simulates the p.f. combustion process properly for these applications.

Original languageEnglish
Pages (from-to)907-912
Number of pages6
JournalFuel
Volume72
Issue number7
DOIs
Publication statusPublished - 1993
Externally publishedYes

Keywords

  • combustion
  • inertinite
  • macerals

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