Real-time in situ X-ray diffraction of intercalation reactions

Simon M. Clark; John S O Evans; Dermot O'Hare; Chris J. Nuttall; Heng Vee Wong

doi:10.1039/C39940000809

Real-time in situ X-ray diffraction of intercalation reactions

Simon M. Clark, John S O Evans, Dermot O'Hare^*, Chris J. Nuttall, Heng Vee Wong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Real-time in situ energy dispersive X-ray powder diffraction techniques have been developed to monitor the intercalation of a guest species into a solid host; the time dependence of the extent of reaction (α) for the intercalation of cobaltocene CoCp₂ (Cp = η⁵-C ₅H₅) by SnS₂ has been experimentally determined and is consistent with a model involving nucleation followed by two-dimensional diffusion of the metallocene molecules into the host lattice.

Original language	English
Pages (from-to)	809-810
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C39940000809
Publication status	Published - 1994
Externally published	Yes

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10.1039/C39940000809

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title = "Real-time in situ X-ray diffraction of intercalation reactions",

abstract = "Real-time in situ energy dispersive X-ray powder diffraction techniques have been developed to monitor the intercalation of a guest species into a solid host; the time dependence of the extent of reaction (α) for the intercalation of cobaltocene CoCp2 (Cp = η5-C 5H5) by SnS2 has been experimentally determined and is consistent with a model involving nucleation followed by two-dimensional diffusion of the metallocene molecules into the host lattice.",

author = "Clark, \{Simon M.\} and Evans, \{John S O\} and Dermot O'Hare and Nuttall, \{Chris J.\} and Wong, \{Heng Vee\}",

year = "1994",

doi = "10.1039/C39940000809",

language = "English",

pages = "809--810",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Real-time in situ X-ray diffraction of intercalation reactions

AU - Clark, Simon M.

AU - Evans, John S O

AU - O'Hare, Dermot

AU - Nuttall, Chris J.

AU - Wong, Heng Vee

PY - 1994

Y1 - 1994

N2 - Real-time in situ energy dispersive X-ray powder diffraction techniques have been developed to monitor the intercalation of a guest species into a solid host; the time dependence of the extent of reaction (α) for the intercalation of cobaltocene CoCp2 (Cp = η5-C 5H5) by SnS2 has been experimentally determined and is consistent with a model involving nucleation followed by two-dimensional diffusion of the metallocene molecules into the host lattice.

AB - Real-time in situ energy dispersive X-ray powder diffraction techniques have been developed to monitor the intercalation of a guest species into a solid host; the time dependence of the extent of reaction (α) for the intercalation of cobaltocene CoCp2 (Cp = η5-C 5H5) by SnS2 has been experimentally determined and is consistent with a model involving nucleation followed by two-dimensional diffusion of the metallocene molecules into the host lattice.

UR - https://www.scopus.com/pages/publications/37049077796

U2 - 10.1039/C39940000809

DO - 10.1039/C39940000809

M3 - Article

AN - SCOPUS:37049077796

SN - 0022-4936

SP - 809

EP - 810

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Real-time in situ X-ray diffraction of intercalation reactions

Abstract

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