Rovibrational energy transfer in D2CO

evidence of an intramolecular mechanism from studies of D2CO/N2O collisions

C. P. Bewick*, B. J. Orr

*Corresponding author for this work

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Infrared-ultraviolet double-resonance spectroscopy shows that the high rate of vibrational energy transfer between the ν6 and ν4 vibrational modes of D2CO in D2CO/D2CO collisions is paralleled by efficient transfer in D2CO/N2O collisions. This implies that the mechanism of collision-induced ν6→ν4 transfer in D2CO is predominantly intramolecular, in which vibrational excitation remains within the state-selected species, rather than intermolecular.

Original languageEnglish
Pages (from-to)73-78
Number of pages6
JournalChemical Physics Letters
Volume159
Issue number1
DOIs
Publication statusPublished - 30 Jun 1989

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