Abstract
Infrared-ultraviolet double-resonance spectroscopy shows that the high rate of vibrational energy transfer between the ν6 and ν4 vibrational modes of D2CO in D2CO/D2CO collisions is paralleled by efficient transfer in D2CO/N2O collisions. This implies that the mechanism of collision-induced ν6→ν4 transfer in D2CO is predominantly intramolecular, in which vibrational excitation remains within the state-selected species, rather than intermolecular.
Original language | English |
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Pages (from-to) | 73-78 |
Number of pages | 6 |
Journal | Chemical Physics Letters |
Volume | 159 |
Issue number | 1 |
DOIs | |
Publication status | Published - 30 Jun 1989 |