Scaling limits to large area perovskite solar cell efficiency

Ben Wilkinson, Nathan L. Chang, Martin A. Green, Anita W. Y. Ho-Baillie*

*Corresponding author for this work

Research output: Contribution to journalConference paper

11 Citations (Scopus)

Abstract

Perovskite solar cells have demonstrated efficiencies over 20%, but this has not been reproduced at large areas. We explore the theoretical limit to single large area perovskite solar cell efficiency, with different front conductive layers: first, the standard n-i-p structure with a transparent conductive electrode (TCE) at the substrate, and then structures that include a front metal grid. We model and optimize the impact of the thickness of the TCE and the dimensions of the grid elements to balance series resistance, parasitic absorption in the TCE layer, and shading losses to maximize efficiency. The results of the optimization suggest that the efficiency of the standard design can be significantly improved simply by selecting the optimum TCE thicknesses for the cell size. However, the poor scaling of the standard design prevents the fabrication of efficient large area cells. Adding a metal grid allows the efficiency of large area cells (156 mm × 156 mm) to approach that of small cells and exceed 20%. The maximum efficiency is limited by the minimum width of the metal grid elements and the sheet resistance of the metal grid material. In this context, the performances of fluorine-doped tin oxide and indium tin oxide as TCE materials were compared, with indium tin oxide found to be superior. We also explore the limits of performance when connecting multiple cells in series to form a large area minimodule and determine the conditions when a front grid is beneficial. Design rules are presented that allow researchers to calculate the optimum cell parameters for high efficiency.

Original languageEnglish
Pages (from-to)659-674
Number of pages16
JournalProgress in Photovoltaics: Research and Applications
Volume26
Issue number8
DOIs
Publication statusPublished - Aug 2018
Externally publishedYes
EventEuropean Photovoltaic Solar Energy Conference and Exhibition (33rd : 2017) - Amsterdam, Netherlands
Duration: 25 Sep 201729 Sep 2017

Keywords

  • grid design
  • large area
  • optimization
  • perovskite
  • scaling

Fingerprint Dive into the research topics of 'Scaling limits to large area perovskite solar cell efficiency'. Together they form a unique fingerprint.

Cite this