Scandium speciation in a world-class lateritic deposit

Mathieu Chasse, William Griffin, Suzanne Y O'Reilly, Georges Calas

Research output: Contribution to journalArticle

31 Citations (Scopus)
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Abstract

Scandium (Sc) has unique properties, highly valued for many applications. Future supply is expected to rely on unusually high-grade (up to 1000 ppm) lateritic Sc ores discovered in Eastern Australia. To understand the origin of such exceptional concentrations, we investigated Sc speciation in one of these deposits. The major factors are unusually high concentrations in the parent rock together with lateritic weathering over long time scales in a stable tectonic context. At microscopic and atomic scales, by combining X-ray absorption near-edge structure spectroscopy, X-ray diffraction and microscopic and chemical analyses, we show that Sc-rich volumes are associated with iron oxides. In particular, Sc adsorbed on goethite accounts for ca. 80 % of the Sc budget in our samples. The remaining Sc is incorporated in the crystal structure of haematite, substituting for Fe3+. Scandium grades reflect the high capacity of goethite to adsorb this element. In contrast, the influence of haematite is limited by the low levels of Sc that its structure can incorporate. These crystal-chemical controls play a major role in lateritic Sc deposits developed over ultramafic–mafic rocks.
Original languageEnglish
Pages (from-to)105–114
Number of pages10
JournalGeochemical Perspectives Letters
Volume3
Issue number2
Early online date23 Nov 2016
DOIs
Publication statusPublished - 2017

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