Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study

Rupak Banik; Subhadip Roy; Ľubor Dlháň; Ján Titiš; Roman Boča; Alexander M. Kirillov; Adam D. Martin; Antonio Bauza; Antonio Frontera; Antonio Rodríguez-Diéguez; Juan M. Salas; Subrata Das

doi:10.1039/c6dt03139k

Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study

Rupak Banik, Subhadip Roy, Ľubor Dlháň, Ján Titiš, Roman Boča, Alexander M. Kirillov, Adam D. Martin, Antonio Bauza, Antonio Frontera, Antonio Rodríguez-Diéguez, Juan M. Salas, Subrata Das

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A new iron(III) complex [Fe(H₂Vi)₃]·py·4H₂O (1) {H₃Vi = violuric acid, py = pyridine} was self-assembled and characterized. In the crystal structure, adjacent [Fe(H₂Vi)₃] blocks are H-bonded into a complex 3D network, which was topologically classified as a pcu [alpha-Po primitive cubic] network. Importance of π-stacking interactions was also highlighted and analyzed computationally. Magnetic studies confirmed antiferromagnetic exchange coupling, while ZFCM/FCM experiments indicated an ordering temperature T_c = 50 K. Finally, magnetic hysteresis at 5 K possesses the coercive field of B_c = 69 mT.

Original language	English
Pages (from-to)	16166-16172
Number of pages	7
Journal	Dalton Transactions
Volume	45
Issue number	41
DOIs	https://doi.org/10.1039/c6dt03139k
Publication status	Published - 2016
Externally published	Yes

Access to Document

10.1039/c6dt03139k

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84992170615&doi=10.1039%2fc6dt03139k&partnerID=40&md5=edf72ede2e348cc7920a73f95af492f5

Cite this

Banik, R., Roy, S., Dlháň, Ľ., Titiš, J., Boča, R., Kirillov, A. M., Martin, A. D., Bauza, A., Frontera, A., Rodríguez-Diéguez, A., Salas, J. M., & Das, S. (2016). Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study. Dalton Transactions, 45(41), 16166-16172. https://doi.org/10.1039/c6dt03139k

@article{a35ba898c7a34c66bb0f58e46062c647,

title = "Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study",

abstract = "A new iron(III) complex [Fe(H2Vi)3]·py·4H2O (1) {H3Vi = violuric acid, py = pyridine} was self-assembled and characterized. In the crystal structure, adjacent [Fe(H2Vi)3] blocks are H-bonded into a complex 3D network, which was topologically classified as a pcu [alpha-Po primitive cubic] network. Importance of π-stacking interactions was also highlighted and analyzed computationally. Magnetic studies confirmed antiferromagnetic exchange coupling, while ZFCM/FCM experiments indicated an ordering temperature Tc = 50 K. Finally, magnetic hysteresis at 5 K possesses the coercive field of Bc = 69 mT.",

author = "Rupak Banik and Subhadip Roy and {\v L}ubor Dlh{\'a}{\v n} and J{\'a}n Titi{\v s} and Roman Bo{\v c}a and Kirillov, {Alexander M.} and Martin, {Adam D.} and Antonio Bauza and Antonio Frontera and Antonio Rodr{\'i}guez-Di{\'e}guez and Salas, {Juan M.} and Subrata Das",

year = "2016",

doi = "10.1039/c6dt03139k",

language = "English",

volume = "45",

pages = "16166--16172",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "41",

}

Banik, R, Roy, S, Dlháň, Ľ, Titiš, J, Boča, R, Kirillov, AM, Martin, AD, Bauza, A, Frontera, A, Rodríguez-Diéguez, A, Salas, JM & Das, S 2016, 'Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study', Dalton Transactions, vol. 45, no. 41, pp. 16166-16172. https://doi.org/10.1039/c6dt03139k

TY - JOUR

T1 - Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative

T2 - a combined experimental and theoretical study

AU - Banik, Rupak

AU - Roy, Subhadip

AU - Dlháň, Ľubor

AU - Titiš, Ján

AU - Boča, Roman

AU - Kirillov, Alexander M.

AU - Martin, Adam D.

AU - Bauza, Antonio

AU - Frontera, Antonio

AU - Rodríguez-Diéguez, Antonio

AU - Salas, Juan M.

AU - Das, Subrata

PY - 2016

Y1 - 2016

N2 - A new iron(III) complex [Fe(H2Vi)3]·py·4H2O (1) {H3Vi = violuric acid, py = pyridine} was self-assembled and characterized. In the crystal structure, adjacent [Fe(H2Vi)3] blocks are H-bonded into a complex 3D network, which was topologically classified as a pcu [alpha-Po primitive cubic] network. Importance of π-stacking interactions was also highlighted and analyzed computationally. Magnetic studies confirmed antiferromagnetic exchange coupling, while ZFCM/FCM experiments indicated an ordering temperature Tc = 50 K. Finally, magnetic hysteresis at 5 K possesses the coercive field of Bc = 69 mT.

AB - A new iron(III) complex [Fe(H2Vi)3]·py·4H2O (1) {H3Vi = violuric acid, py = pyridine} was self-assembled and characterized. In the crystal structure, adjacent [Fe(H2Vi)3] blocks are H-bonded into a complex 3D network, which was topologically classified as a pcu [alpha-Po primitive cubic] network. Importance of π-stacking interactions was also highlighted and analyzed computationally. Magnetic studies confirmed antiferromagnetic exchange coupling, while ZFCM/FCM experiments indicated an ordering temperature Tc = 50 K. Finally, magnetic hysteresis at 5 K possesses the coercive field of Bc = 69 mT.

UR - http://www.scopus.com/inward/record.url?scp=84992170615&partnerID=8YFLogxK

U2 - 10.1039/c6dt03139k

DO - 10.1039/c6dt03139k

M3 - Article

C2 - 27722577

SN - 1477-9226

VL - 45

SP - 16166

EP - 16172

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study

Abstract

Access to Document

Other files and links

Fingerprint

Cite this