Self-coupling of a 4-H-butatrienylidene tungsten complex

Sergey N. Semenov; Olivier Blacque; Thomas Fox; Koushik Venkatesan; Heinz Berke

doi:10.1002/anie.200901914

Self-coupling of a 4-H-butatrienylidene tungsten complex

Sergey N. Semenov, Olivier Blacque, Thomas Fox, Koushik Venkatesan, Heinz Berke

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Tungsten tryst: A 4-H-butatrienylidene complex of tungsten was successfully isolated and structurally characterized. It undergoes a unique self-coupling, which leads to a dimer (see picture; P pink, O red) with a cross-conjugated π system and with electrochemically and magnetically active metal centers.

Original language	English
Pages (from-to)	5203-5206
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	28
DOIs	https://doi.org/10.1002/anie.200901914
Publication status	Published - 29 Jun 2009
Externally published	Yes

Keywords

π -conjugation
Cumulenes
Dimerization
Molecular devices
Tungsten

Access to Document

10.1002/anie.200901914

Cite this

@article{47e5f90b53b04d69baa147194667353a,

title = "Self-coupling of a 4-H-butatrienylidene tungsten complex",

abstract = "Tungsten tryst: A 4-H-butatrienylidene complex of tungsten was successfully isolated and structurally characterized. It undergoes a unique self-coupling, which leads to a dimer (see picture; P pink, O red) with a cross-conjugated π system and with electrochemically and magnetically active metal centers.",

keywords = "π -conjugation, Cumulenes, Dimerization, Molecular devices, Tungsten",

author = "Semenov, {Sergey N.} and Olivier Blacque and Thomas Fox and Koushik Venkatesan and Heinz Berke",

year = "2009",

month = jun,

day = "29",

doi = "10.1002/anie.200901914",

language = "English",

volume = "48",

pages = "5203--5206",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH, Wiley",

number = "28",

}

TY - JOUR

T1 - Self-coupling of a 4-H-butatrienylidene tungsten complex

AU - Semenov, Sergey N.

AU - Blacque, Olivier

AU - Fox, Thomas

AU - Venkatesan, Koushik

AU - Berke, Heinz

PY - 2009/6/29

Y1 - 2009/6/29

N2 - Tungsten tryst: A 4-H-butatrienylidene complex of tungsten was successfully isolated and structurally characterized. It undergoes a unique self-coupling, which leads to a dimer (see picture; P pink, O red) with a cross-conjugated π system and with electrochemically and magnetically active metal centers.

AB - Tungsten tryst: A 4-H-butatrienylidene complex of tungsten was successfully isolated and structurally characterized. It undergoes a unique self-coupling, which leads to a dimer (see picture; P pink, O red) with a cross-conjugated π system and with electrochemically and magnetically active metal centers.

KW - π -conjugation

KW - Cumulenes

KW - Dimerization

KW - Molecular devices

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=70349898418&partnerID=8YFLogxK

U2 - 10.1002/anie.200901914

DO - 10.1002/anie.200901914

M3 - Article

C2 - 19526481

AN - SCOPUS:70349898418

SN - 1433-7851

VL - 48

SP - 5203

EP - 5206

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 28

ER -

Self-coupling of a 4-H-butatrienylidene tungsten complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this