Self-coupling of a 4-H-butatrienylidene tungsten complex

Sergey N. Semenov, Olivier Blacque, Thomas Fox, Koushik Venkatesan, Heinz Berke

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Tungsten tryst: A 4-H-butatrienylidene complex of tungsten was successfully isolated and structurally characterized. It undergoes a unique self-coupling, which leads to a dimer (see picture; P pink, O red) with a cross-conjugated π system and with electrochemically and magnetically active metal centers.

Original languageEnglish
Pages (from-to)5203-5206
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number28
DOIs
Publication statusPublished - 29 Jun 2009
Externally publishedYes

Keywords

  • π -conjugation
  • Cumulenes
  • Dimerization
  • Molecular devices
  • Tungsten

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