Abstract
The 19-nor-clerodanes are compact, densely functionalized diterpenes based on a stereocentre-rich decalin scaffold. To date only a few examples of the 19-nor-clerodanes have been synthesized, hence new flexible strategies are required. We herein describe the stereocontrolled construction of the cis-hydroxy decalin core in a concise fashion.
Original language | English |
---|---|
Pages (from-to) | 1633-1638 |
Number of pages | 6 |
Journal | European Journal of Organic Chemistry |
Volume | 2012 |
Issue number | 8 |
DOIs | |
Publication status | Published - Mar 2012 |
Externally published | Yes |
Keywords
- natural products
- total synthesis
- terpenoids
- crotonin
- spiro compounds
- electrocyclization