Studies in H2O + D2O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H2O + D2O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion

Barry D. Batts; John Kilford

doi:10.1039/F19736901033

Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion

Barry D. Batts^*, John Kilford

^*Corresponding author for this work

Faculty of Science and Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The kinetics of the hydrogen exchange reaction between 1,3,5-trimethoxy[2- ³H]benzene and aqueous 0.05 M perchloric acid in H₂O + D₂O mixtures have been studied. The results are used to calculate the value for the isotopic fractionation of the hydrogen ion (l). Nine other systems already reported are similarly treated and a probable value for l is given as 0.72 ± 0.01.

Original language	English
Pages (from-to)	1033-1038
Number of pages	6
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	69
DOIs	https://doi.org/10.1039/F19736901033
Publication status	Published - 1973

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Batts, B. D., & Kilford, J. (1973). Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 69, 1033-1038. https://doi.org/10.1039/F19736901033

Batts, Barry D. ; Kilford, John. / Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures : Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion. In: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 1973 ; Vol. 69. pp. 1033-1038.

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title = "Studies in H2O + D2O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H2O + D2O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion",

abstract = "The kinetics of the hydrogen exchange reaction between 1,3,5-trimethoxy[2- 3H]benzene and aqueous 0.05 M perchloric acid in H2O + D2O mixtures have been studied. The results are used to calculate the value for the isotopic fractionation of the hydrogen ion (l). Nine other systems already reported are similarly treated and a probable value for l is given as 0.72 ± 0.01.",

author = "Batts, {Barry D.} and John Kilford",

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Batts, BD & Kilford, J 1973, 'Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion', Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol. 69, pp. 1033-1038. https://doi.org/10.1039/F19736901033

Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion. / Batts, Barry D.; Kilford, John.
In: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 69, 1973, p. 1033-1038.

Research output: Contribution to journal › Article › peer-review

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AU - Kilford, John

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N2 - The kinetics of the hydrogen exchange reaction between 1,3,5-trimethoxy[2- 3H]benzene and aqueous 0.05 M perchloric acid in H2O + D2O mixtures have been studied. The results are used to calculate the value for the isotopic fractionation of the hydrogen ion (l). Nine other systems already reported are similarly treated and a probable value for l is given as 0.72 ± 0.01.

AB - The kinetics of the hydrogen exchange reaction between 1,3,5-trimethoxy[2- 3H]benzene and aqueous 0.05 M perchloric acid in H2O + D2O mixtures have been studied. The results are used to calculate the value for the isotopic fractionation of the hydrogen ion (l). Nine other systems already reported are similarly treated and a probable value for l is given as 0.72 ± 0.01.

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SN - 0300-9599

VL - 69

SP - 1033

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JO - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

JF - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

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Batts BD, Kilford J. Studies in H₂O + D₂O media. Part 1. - Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: Re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 1973;69:1033-1038. doi: 10.1039/F19736901033