Abstract
This study aims to investigate the nature and type of complexes formed in solution between 1,2-bis(2,6-dimethphenylamino) glyoxime (DPG) and the ions Ni2+, Cu2+ and Zn2+. Potentiometric titration was used to follow the formation of complexes.
The complexes formed were studied through the determination of stability constants of these complexes in mixed ethanol-aqueous solution at 25 +/- 0.1 A degrees C and ionic strength of 0.1 mola
Comparison with other vic-dioximes was made to provide reliable support for the formation of the proposed complexes in solution.
| Original language | English |
|---|---|
| Pages (from-to) | 1618-1628 |
| Number of pages | 11 |
| Journal | Journal of Solution Chemistry |
| Volume | 40 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - Sept 2011 |
| Externally published | Yes |
Keywords
- Vic-dioxime
- Potentiometric titration
- Metal complexes
- Stability constants
- SUPERQUAD
- Dissociation constants
- VIC-DIOXIME LIGAND
- NICKEL(II)
- CHEMISTRY
- MODEL
- SOLUBILITY
- SPECTRA
- BONDS
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