Supported Rh catalysts for the indirect partial oxidation of isooctane

Praharso; Adesoji A. Adesina; David L. Trimm; Noel W. Cant

Supported Rh catalysts for the indirect partial oxidation of isooctane

Praharso, Adesoji A. Adesina, David L. Trimm^*, Noel W. Cant

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The production of hydrogen from isooctane over three rhodium-based catalysts has been examined. The reaction entailed total oxidation of a proportion of the fuel followed by reforming of isooctane to produce hydrogen. Rhodium (1% wt) was impregnated on three different supports: alumina, ceria-alumina, and ceria-zirconia. No differences in catalytic activity were observed, but reaction yield changed with the support. Ceria-zirconia was found to be the preferred support since methanation did not occur over the catalyst.

Original language	English
Pages (from-to)	468-470
Number of pages	3
Journal	Korean Journal of Chemical Engineering
Volume	20
Issue number	3
Publication status	Published - May 2003

Keywords

Gasoline
Isooctane
Partial Oxidation
Sol-gel
TPO

Cite this

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title = "Supported Rh catalysts for the indirect partial oxidation of isooctane",

abstract = "The production of hydrogen from isooctane over three rhodium-based catalysts has been examined. The reaction entailed total oxidation of a proportion of the fuel followed by reforming of isooctane to produce hydrogen. Rhodium (1% wt) was impregnated on three different supports: alumina, ceria-alumina, and ceria-zirconia. No differences in catalytic activity were observed, but reaction yield changed with the support. Ceria-zirconia was found to be the preferred support since methanation did not occur over the catalyst.",

keywords = "Gasoline, Isooctane, Partial Oxidation, Sol-gel, TPO",

author = "Praharso and Adesina, {Adesoji A.} and Trimm, {David L.} and Cant, {Noel W.}",

year = "2003",

month = may,

language = "English",

volume = "20",

pages = "468--470",

journal = "Korean Journal of Chemical Engineering",

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TY - JOUR

T1 - Supported Rh catalysts for the indirect partial oxidation of isooctane

AU - Praharso,

AU - Adesina, Adesoji A.

AU - Trimm, David L.

AU - Cant, Noel W.

PY - 2003/5

Y1 - 2003/5

N2 - The production of hydrogen from isooctane over three rhodium-based catalysts has been examined. The reaction entailed total oxidation of a proportion of the fuel followed by reforming of isooctane to produce hydrogen. Rhodium (1% wt) was impregnated on three different supports: alumina, ceria-alumina, and ceria-zirconia. No differences in catalytic activity were observed, but reaction yield changed with the support. Ceria-zirconia was found to be the preferred support since methanation did not occur over the catalyst.

AB - The production of hydrogen from isooctane over three rhodium-based catalysts has been examined. The reaction entailed total oxidation of a proportion of the fuel followed by reforming of isooctane to produce hydrogen. Rhodium (1% wt) was impregnated on three different supports: alumina, ceria-alumina, and ceria-zirconia. No differences in catalytic activity were observed, but reaction yield changed with the support. Ceria-zirconia was found to be the preferred support since methanation did not occur over the catalyst.

KW - Gasoline

KW - Isooctane

KW - Partial Oxidation

KW - Sol-gel

KW - TPO

UR - http://www.scopus.com/inward/record.url?scp=0042744706&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0042744706

SN - 0256-1115

VL - 20

SP - 468

EP - 470

JO - Korean Journal of Chemical Engineering

JF - Korean Journal of Chemical Engineering

IS - 3

ER -

Supported Rh catalysts for the indirect partial oxidation of isooctane

Abstract

Keywords

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